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Unveiling nontrivial fusion rule of Majorana zero mode using a fermionic mode

Yu Zhang School of Physics, MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter, Xi’an Jiaotong University, Xi’an 710049, China    Xiaoyu Zhu School of Physics, MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter, Xi’an Jiaotong University, Xi’an 710049, China    Chunhui Li School of Physics, MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter, Xi’an Jiaotong University, Xi’an 710049, China    Juntao Song Department of Physics and Hebei Advanced Thin Film Laboratory, Hebei Normal University, Shijiazhuang 050024, China    Jie Liu School of Physics, MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter, Xi’an Jiaotong University, Xi’an 710049, China Hefei National Laboratory, Hefei 230088, China    X. C. Xie International Center for Quantum Materials, School of Physics, Peking University, Beijing 100871, China Institute for Nanoelectronic Devices and Quantum Computing, Fudan University, Shanghai 200438, China Hefei National Laboratory, Hefei 230088, China
Abstract

Fusing Majorana zero modes leads to multiple outcomes, a property being unique to non-Abelian anyons. Successful demonstration of this nontrivial fusion rule would be a hallmark for the development of topological quantum computation. Here we show that this can be done by simply attaching a fermionic mode to a single Majorana zero mode. Through modulation of the energy level of this fermionic mode as well as its coupling with the Majorana mode in different sequences, we show that a zero or integer charge pumping can be realized when different fusion loops are chosen. Such fusion loops are intimately related with the nontrivial fusion rule of Majorana modes and are solely determined by the crossings at zero energy in the parameter space. Finally we demonstrate our proposal in a nanowire-based topological superconductor coupled to a quantum dot. We show that the charge pumping is robust for MZMs in the real system irrespective of the initial condition of FM state, contrary to the case for trivial Andreev bound states. This provides a feasible way to distinguish Majorana modes from trivial Andreev bound states.

pacs:
74.45.+c, 74.20.Mn, 74.78.-w
preprint: APS/123-QED

Introduction. It has been a long-cherished dream of condensed matter physicists to find Majorana zero mode (MZM) for its potential application in fault-tolerant topological quantum computations kitaev ; nayak . Despite overwhelming evidences in favor of MZMs being reported over the last decade Fu ; sau ; fujimoto ; sato ; alicea2 ; lut ; 2DEG1 ; 2DEG2 ; kou ; deng ; das1 ; hao1 ; Marcus ; deng2 ; perge ; Yaz2 ; Jia ; Fes1 ; Fes2 ; PJJ1 ; PJJ2 , there is still room for other possible interpretations in regards to experimental results of various studies, such as the existence of Andreev bound states (ABS)Jie1 ; brouwer ; Aguado ; ChunXiao1 ; Moore ; Wimmer ; Aguado2 ; Pan ; ABSM . While it’s possible for ABS to demonstrate a great deal of similarities to MZMs in transport experiments, the two are fundamentally different particles in terms of the exchange statistics they obey, which could be exploited to discriminate them Ivanov ; alicea3 ; NQP ; Jienew .

In contrast to ABS which are ordinary fermions, MZMs follow non-Abelian statistics. This non-Abelian property reveals itself in two distinct but closely related aspects. First, in a system of MZMs, their quantum state may experience a nontrivial rotation when two of them are exchanged, unlike ABS or other Abelian anyons where the state only acquires a global phase. More importantly, two consecutive rotations in differing sequences may incur totally different final states, hence the name non-Abelian. Such rotations, or braiding operations, constitute the basic logic gates of topological quantum computations, with various theoretical studies being devoted to in the last decadesTQC2 ; TQC3 ; TQC4 ; MSQ ; net1 ; net2 ; Yu1 ; Sato ; Roy ; QD1 . Besides the braiding, fusion is another equally important non-abelian property of MZMsnayak . For MZMs, two of them can fuse into a particle of trivial type II or a fermion Ψ\Psi, with the fusion rule formally expressed as γ×γ=I+Ψ\gamma\times\gamma=I+\Psi. Since the outcome is multiple, the final fusion results would rely on the fusion order of MZMs. In principle, since fusion is actually a process that couple two MZMs with finite energy, it should be easier to realize in experiment compared with braiding. Several pioneer work have suggested that fusion would induce nontrivial charge transport fusion1 ; fusion2 ; fusion3 . However, the protocols are still complicated for further investigation.

In this paper, we propose to unveil the nontrivial fusion rule of MZMs by simply attaching a fermionic mode (FM) to a single MZM. Such a setup could be possibly realized in multiple systems, for instance, in a nanowire based topological superconductor (TS) that is coupled to a quantum dot deng2 (see Fig. 1(a)), or in a topologically nontrivial vortex with a molecule attached to scanning probe microscopy acting as the FM Jievortex . The FM can usually be deemed as two pre-fused MZMs γA\gamma_{A} and γB\gamma_{B} with the hybridization energy EdE_{d}. As such, these two MZMs can be effectively split by tuning EdE_{d} to zero. The fusion and splitting process between γB\gamma_{B} and another MZM γ1\gamma_{1} in the TS can be controlled by tuning the coupling between the FM and the superconductor, as schematically depicted in Fig. 1(a). This is because MZM is its own anti-particle, and γ1\gamma_{1} only couples to half of the FM γB\gamma_{B} Jienew . Based on these observations, different fusion and splitting processes can be realized through tuning the energy level of FM or adjusting the coupling between MZM and FM. Recent experiments have demonstrated that these parameters can be easily modulated using gate voltage Pkitaev ; Pgate1 ; Pgate2 , making our fusion protocol feasible for practical systems. Furthermore, these nontrivial fusion processes could induce significant charge transfer events, which can be precisely detected using charge sensing methods charge .

Refer to caption
Figure 1: (a) A coupled quantum dot (QD) nanowire (NW) system that could demonstrate our fusion protocol. Quantum dot provides the fermionic mode (equivalent to two MZMs) needed while the unpaired Majorana zero modes are expected to appear at the ends of superconducting nanowire. (b) The fusion rule of two MZMs. Two fusion outcomes, vacuum state II and unpaired fermionic state Ψ\Psi, appear with equal probability. (c) For a typical trivial loop (left panel), we first split γA\gamma_{A} and γB\gamma_{B} (FAB1F_{AB}^{-1}), followed by the fusion of γB\gamma_{B} and γ1\gamma_{1} (FB1F_{B1}), and then reverse the operation to complete the loop. In a typical nontrivial loop (right panel), two consecutive processes do not commute with each other.

Model-independent Hamiltonian of the setup and the current formula. To simulate the fusion process of MZMs, we start from a model-independent Hamiltonian:

Hs=2Ed(t)dd+[tc(t)dtc(t)d]γ1+iEMγ1γ2,H_{s}={2E_{d}(t)}{d^{\dagger}}d+[{t_{c}(t)}d-t_{c}(t)^{*}{d^{\dagger}}]{\gamma_{1}}+iE_{M}{\gamma_{1}}{\gamma_{2}}, (1)

where dd is the annihilation operator of FM, and EdE_{d} is the on-site energy of FM. γ1\gamma_{1} and γ2\gamma_{2} are a pair of MZMs coming from TS, and EME_{M} represents the coupling between them. The coupling between FM and γ1\gamma_{1} is denoted by tc=|tc|eiϕ/2t_{c}=|t_{c}|e^{i\phi/2}, in which ϕ\phi is the pairing phase of TS S1 . By decomposing FM operator into superposition of two MZMs, d=12eiϕ2(γA+iγB)d=\frac{1}{2}e^{-i\frac{\phi}{2}}(\gamma_{A}+i\gamma_{B}), Hamiltonian in Eq.(1) can be rewritten in the following simple form:

HM\displaystyle H_{M} =iEdγAγB+i|tc|γBγ1+iEMγ1γ2.\displaystyle=i{E_{d}}\gamma_{A}\gamma_{B}+i|t_{c}|\gamma_{B}{\gamma_{1}}+iE_{M}{\gamma_{1}}{\gamma_{2}}. (2)

From Eq.(S6) we note EdE_{d}, EME_{M} and tct_{c} can be treated as couplings between different MZMs. This suggests that one could simulate fusion process by tuning these parameters from zero to a finite value, and vice veresa.

The charge transfer of FM can be defined as the integration of the time-dependent current from FM to TS, i.e., δN(t)=0tJ^e(τ)+J^h(τ)dτ\delta N(t)=\int_{0}^{t}\langle\hat{J}_{e}(\tau)+\hat{J}_{h}(\tau)\rangle\mathrm{d}\tau Jie2 ; Lei , with

J^e(h)(t)=i2Tr(ψde(t)|Hce(h)(t)|ψMe(h)(t)+h.c.)\langle\hat{J}_{e(h)}(t)\rangle=-\frac{i}{2}Tr(\langle\psi_{d}^{e}(t)|H_{c}^{e(h)}(t)|\psi_{M}^{e(h)}(t)\rangle+h.c.) (3)

Here, |ψde(t)|\psi_{d}^{e}(t)\rangle is the electron part wavefunction of FM at time tt, and |ψMe(h)(t)|\psi_{M}^{e(h)}(t)\rangle is the electron (hole) part wavefunction of MZMs at time tt. Hce(t)=tc(t)2dΨMH_{c}^{e}(t)=\frac{t_{c}(t)}{2}d\Psi_{M}^{{\dagger}} and Hch(t)=tc(t)2dΨMH_{c}^{h}(t)=\frac{t_{c}(t)}{2}d\Psi_{M}, representing two different parts of tct_{c} coupling term in Eq.(1), with fermionic state ΨM=γ1+iγ2\Psi_{M}=\gamma_{1}+i\gamma_{2}. Equation (3) suggests that our system supports two charge transfer processes. The first one, JeJ_{e}, involves an electron hopping from FM to MZM or vice versa (termed as TE process). During the process represented by JhJ_{h}, an electron in FM transforms into a hole in MZM (termed as TH process). Which of the two processes to occur is determined by fermion parity of the system.

Refer to caption
Figure 2: (a) The charge transfer for the nontrivial loop FAB1FB1FABFB11F_{AB}^{-1}F_{B1}F_{AB}F_{B1}^{-1}. Here FAB1F_{AB}^{-1} (FABF_{AB}) is controlled by Ed(t)=E0[a±cos(ωt)]E_{d}(t)=E_{0}[a\pm\cos(\omega t)] with ω=1/1000 mev\omega=1/1000\text{ mev}, T=π/ωT=\pi/\omega, and EM=109 mevE_{M}=10^{-9}\text{ mev}. After the splitting process, the energy level of the FM reaches exactly to zero for a=1a=1, stays above zero for a=1.1a=1.1, and changes sign for a=0.9a=0.9. (b) The charge transfer for the trivial loop FAB1FB1FB11FABF_{AB}^{-1}F_{B1}F_{B1}^{-1}F_{AB}. (c) and (d) show the evolution of system parameters corresponding to (a) and (b), respectively.

Nontrivial fusion loop and the related charge transfer. Due to the nontrivial fusion rule of MZMs, the fusion outcomes would rely on their fusion order. To distinguish between fusion and splitting processes, we denote the fusion of MZM ii and MZM jj as FijF_{ij}, and the splitting process as Fij1F_{ij}^{-1}. It is clear that when fusion and splitting of two MZMs occur consecutively, the end result is trivial, i.e., Fij1Fij=IF_{ij}^{-1}F_{ij}=I. A minimal model illustrating the nontrivial fusion rule requires at least four MZMs. The left loop in Fig. 1(c) depicts a prototypical trivial loop for this minimal model since FAB1FB1FB11FAB=IF_{AB}^{-1}F_{B1}F_{B1}^{-1}F_{AB}=I. A nontrivial fusion loop, however, requires two consecutive processes to be non-commute, such that the final state cannot return to the initial one after a complete loop. Based on this rule, many nontrivial loops can be designed by manipulating the order of fusion and splitting processes. The right loop in Fig. 1(c) illustrates a representative nontrivial loop, denoted by FAB1FB1FABFB11F_{AB}^{-1}F_{B1}F_{AB}F_{B1}^{-1}, which is similar to the one introduced in Ref. fusion1, . However, in this new proposal we need not tune the parameters in the TS system, which may avoid unwanted adverse effects due to the manipulation of TS wires.

Refer to caption
Figure 3: The charge pumping would be nontrivial if the parameters EdE_{d} and tct_{c} cross at zero energy with odd times. (a) and (b) show the corresponding charge transfer for paths depicted in (c) and (d). These paths only differ in how tct_{c} evolves in the corresponding fusion loop. Clearly, EdE_{d} and tct_{c} cross at zero energy with an odd number of times in path 1 and 2.

To validate our proposal, we numerically calculate the charge transfer during both the trivial and the nontrivial loops. The splitting of the two MZMs that constitute the FM is controlled by EdE_{d}, which we assume to vary with time according to Ed(t)=E0[a+cos(ωt)]E_{d}(t)=E_{0}[a+\cos(\omega t)] with a=1a=1. This suggests that the FM would initiate with energy 2E02E_{0} at ωt=0\omega t=0 and split at zero energy at ωt=π\omega t=\pi. The fusion process is just the reverse of this process with Ed(t)=E0[1cos(ωt)]E_{d}(t)=E_{0}[1-\cos(\omega t)]. Similarly, tc(t)=|E0|[1±cos(ωt)]t_{c}(t)=|E_{0}|[1\pm\cos(\omega t)] controls the splitting and fusion process of γB\gamma_{B} and γ1\gamma_{1}. At initial time we have Ed=2E0>0E_{d}=2E_{0}>0 and thus the system is in |0AB012|0_{\text{AB}}0_{12}\rangle state. We may calculate the charge transfer for the nontrivial loop denoted by FAB1FB1FABFB11F_{AB}^{-1}F_{B1}F_{AB}F_{B1}^{-1}. According to the nontrivial fusion rule of MZMs, two MZMs would fuse either as a vacuum state II or an unpaired fermionic state Ψ\Psi. The system’s state thus shifts to a superposition of |0AB012|0_{\text{AB}}0_{12}\rangle and |1AB112|1_{\text{AB}}1_{12}\rangle, implying a half charge transferring from TS to FM. As revealed by the yellow dashed line in Fig. 2(a), a half charge indeed transfers from TS to FM after a complete loop. However, a FM state is usually not stable at the zero energy. If EdE_{d} remains positive, the splitting process would not happen and the system simply returns to |0AB012|0_{\text{AB}}0_{12}\rangle state after one period. In this case, there’s no charge transfer as revealed by the red solid line shown in Fig. 2(a), even though the deviation is small (the corresponding Ed(t)E_{d}(t) is shown by the red solid line in Fig. 2(c)). If instead the energy of the FM crosses zero, say for a=0.9a=0.9, the FM state would switch to the occupied state |1AB|1_{\text{AB}}\rangle, and the whole system would choose |1AB112|1_{\text{AB}}1_{12}\rangle finally due to the conservation of fermion parity. This results in an integer charge transferring from FM to MZMs after one complete loop as red solid line in Fig. 2(a) shows. Such a nontrivial pumping cannot happen in the trivial loop denoted by FAB1FB1FB11FABF_{AB}^{-1}F_{B1}F_{B1}^{-1}F_{AB}, where the net charge transfer is always zero as indicated by Fig. 2(b), regardless whether EdE_{d} crosses zero level during the whole process as can be seen in Fig. 2(d).

Since the splitting of MZMs γA\gamma_{A} and γB\gamma_{B} takes place at Ed=0E_{d}=0, the system parameters at this moment play a pivotal role in determining the occurrence of nontrivial pumping. As indicated by path 1 in Fig. 3(c), we set Ed(t)=+()E0cos(ωt)E_{d}(t)=+(-)E_{0}\cos(\omega t) for t[0,T](t[2T,3T])t\in[0,T](t\in[2T,3T]). In this situation, the final fusion energy of MZM transitions from 2E02E_{0} to E0E_{0}, while Ed(t)E_{d}(t) and tc(t)t_{c}(t) both stay at zero energy at t=T/2t=T/2 (or ωt=π/2)\omega t=\pi/2) and the parameters cross one time as indicated by the circle. Consequently, an integer charge is transferred as revealed by the red solid line in Fig. 3(a), which is independent of the final fusion energy. However, if we fuse γB\gamma_{B} and γ1\gamma_{1} before Ed(t)E_{d}(t) reaches zero (path 2 in Fig. 3(c)), the net charge transfer would be zero after the loop is completed. This suggests that the nontrivial charge transfer directly relate to the crossing between EdE_{d} and tct_{c} at zero energy in the parameter space. Intriguingly, path 3 mirrors path 1 but with an extra intersection of Ed(t)E_{d}(t) and tc(t)t_{c}(t) at zero energy (shown by the red dashed line in Fig. 3(d)). This results in the charge transfer reverting to zero. Conversely, by varying tc(t)t_{c}(t) as depicted in path 4 of Fig. 3(d), where only a single zero-energy crossing occurs, the final charge transfer would remain to be one, as seen in Fig. 3(c). These results suggest a simple criterion for nontrivial charge pumping: if Ed(t)E_{d}(t) and tc(t)t_{c}(t) intersect at zero energy an odd number of times in a closed loop, the charge pumping becomes nontrivial. Conversely, an even number of such intersections within the interval results in trivial charge pumping. This observation holds potential to guide experimental manipulations. Practically, tuning tct_{c} to zero may pose a primary challenge in our proposal. However, we expect the nontrivial pumping to be observed when the time period T1/min(tc)T\ll 1/\min(t_{c}), where min(tc)\min(t_{c}) represents the minimum value of tct_{c} at the moment of intersection. Note that tct_{c} is determined by the tunneling barrier and usually decays exponentially with barrier size, which can be modulated by gate voltage. Adiabatic evolution further requires T1/ΔT\gg 1/\Delta. As a result, the time window for the nontrivial pumping is 1/ΔT1/min(tc)1/\Delta\ll T\ll 1/\min(t_{c}).

Refer to caption
Figure 4: (a) Schematic plot of unpaired MZMs (upper) and ABS (lower) in a nanowire. We use a hard wall confinement to introduce ABS (a step-like potential depicted as the black line). (b) Evolution of energy spectrum with external magnetic field in the NS system. The red dashed line indicates the topological phase transition points. On the left side, the system is in the trivial regime, with ABS localized at the interface. (c) The variation of charge pumping with external magnetic field in the NS system according the parameters of (f). (d) The charge transfer process for Vx=0.7 mevV_{x}=0.7\text{ mev} (cyan cut in (b)), Vx=0.35 mevV_{x}=0.35\text{ mev} (green cut in (b)), and Vx=0.25 mevV_{x}=0.25\text{ mev} (red cut in (b)), with EdE_{d} and tct_{c} varying according to (f). (e) The charge pumping versus time tt for three representative cases as in (d). The variations of the parameters EdE_{d} and tct_{c} with time are depicted in (g). Here FM is occupied, and therefore the charge pumping is from FM to TS.

Numerical simulation in the nanowire superconducting nanowire. We have shown that the nontrivial charge pumping would be induced through controlling the order of both fusion and splitting processes among the MZMs. Naturally, one may wonder how ABS and MZM differ during this process. To investigate this, we further simulate the non-Abelian fusion processes in a realistic nanowire/superconductor (NS) system as depicted in Fig. 4(a). In general, the ABS state may arise due to inhomogeneous potential or disorder at the interface of the NS system S3 . Here, we introduce a typical hard wall confinement at the end of the NS to model the inhomogeneous potential. This results in a nearly zero-energy ABS state being trapped at the left end of NS before the system is driven into topologically nontrivial phases by increasing Zeeman energy VxV_{x}, as shown in Fig. 4(b). In practice, the chemical potential of the FM can be modulated through gate voltage as demonstrated in recent experiment, so is the coupling between the FM and the NS system Pgate1 ; Pgate2 . Thus our fusion protocol could be readily implemented in real systems.

In Fig. 4(c), we show the final charge transfer from FM to TS for the nontrivial loop depicted in Fig. 4(f) when the Zeeman energy VxV_{x} varies, which suggests that ABS states can also introduce nontrivial charge pumping. Representative charge transfer processes are demonstrated in Fig. 4(d) for Vx=0.25V_{x}=0.25 (red line), 0.350.35 (blue line) and 0.70.7 (cyan line). Clearly, an integer charge is transferred when Vx=0.25V_{x}=0.25 and Vx=0.7V_{x}=0.7. For Vx=0.35V_{x}=0.35, however, only a fractional charge is transferred after a complete loop. We may also set E0=0.05 mevE_{0}=-0.05\text{ mev} at t=0t=0 as shown in Fig. 4 (g), where the FM is initially occupied. The resulting charge transfer as shown in Fig. 4(e) is solely determined by the fusion channel of the FM. If the fermionic state is initially unoccupied (corresponding to fusion channel II), the charge should be transferred from MZM to FM. This transfer process will be reversed if the fermionic state is initially occupied (fusion channel Ψ\Psi). Moreover, integer pumping is only robust in the topological region, while the quantized charge pumping for Vx=0.25V_{x}=0.25 is failed for the occupied case and is quantized for Vx=0.35V_{x}=0.35. This means that the quantized charge pumping is robust for MZMs, regardless whether the initial FM state is occupied or unoccupied. As for ABS, it can be divided into two kinds of states. One is the electron-like ABS which can support quantized charge transfer if the initial FM state is occupied. Another one is the hole-like ABS which can support quantized charge transfer if the initial FM state is unoccupied.

The distinct behaviors of MZMs and ABS can be further understood from transport processes. During the fusion, the charge transfers through either TE or TH process, not both (see Supplementary materials for more information), determined by the total parity of the system. To understand this, we first note that the total parity is conserved with the evolution of EdE_{d} and tct_{c}. If the initial state is |0AB012|0_{\text{AB}}0_{12}\rangle which means both the FM and MZM are unoccupied, it would gradually switch to state |1AB112|1_{\text{AB}}1_{12}\rangle after half a period. The TE process, which only transfers electrons between FM and MZM, cannot make it. Hence, the pumping has to be accomplished through TH process, during which a hole in the FM is transformed to an electron in MZM. However, if E0<0E_{0}<0, the initial state would be |1AB012|1_{\text{AB}}0_{12}\rangle instead and only TE process occurs. Since MZM is its own anti-particle, there’s no difference between TE and TH process. While for ABS one of the two processes would be preferred as it is not hermitian.

Conclusion. With the assistance of a fermionic mode, we unveil the fusion rule of MZMs, which manifests itself in the nontrivial charge transfer process. The FM can be easily attached either to the end of 1D TS wire or a vortex in 2D TS system. Moreover, by controlling the order of fusion and splitting processes among MZMs, one may design trivial and nontrivial fusion loops tailored for the convenience of specific platforms since each process can be individually adjusted. Therefore, our proposal can be applied to various TS systems without additional constraints. In our proposal, one only needs to tune the energy level of FM as well as its coupling to the Majorana modes through gate voltages, leaving the parameters of topological superconductor intact. This may avoid potential complications arising from meddling with TS wires. Finally, we emphasize that the charge transfer are distinct for different situation, we can expect that other realistic factors, such as finite temperature or interaction, only play insignificant roles in our setup. Thus, our proposal provides a feasible route for showcasing the nontrivial fusion rules of MZMs.

Acknowledgement. This work is financially supported by National Natural Science Foundation of China (Grants No. 11974271, and No. 92265103), the National Basic Research Program of China (Grants No. 2015CB921102 and No. 2019YFA0308403), and the Innovation Program for Quantum Science and Technology (Grant No. 2021ZD0302400).

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Supplemental Material for “Unveiling non-trivial fusion rule of Majorana zero mode using a fermionic mode”

Appendix A Additional nontrivial fusion loop

As we have shown in the main text, the trivial and nontrivial fusion loops can be designed by manipulating the order of fusion and splitting processes. Contrary to the fusion loop in the main text, here we fuse γB\gamma_{B} and γ1\gamma_{1} first. As such, the trivial loop would be denoted as FB1FAB1FABFB11F_{B1}F_{AB}^{-1}F_{AB}F_{B1}^{-1} and the nontrivial loop could be denoted as FB1FAB1FB11FABF_{B1}F_{AB}^{-1}F_{B1}^{-1}F_{AB}, as shown in Fig. S1(a). The charge transfer for the nontrivial loop shows a zero, half, integer charge pumping in Fig. S1(b) when the corresponding parameters vary as Fig. S1(d) depicts. While for the trivial case the net charge transfer is always zero as indicated by Fig. S1(c), regardless whether EdE_{d} crosses zero level during the whole process, as can be seen in Fig. S1(e). Although it shows the same charge transfer behavior as the charge pumping in Fig. 2 of the main text, the charge pumping here is more stable and does not oscillate in the case Ed=0E_{d}=0 with a=1a=1. This is because the charge would have no definite way to transfer in and out of the FM states at Ed=0E_{d}=0 and display an oscillating behavior when we vary tct_{c} during the loops shown in the main text. Nevertheless the modified loop here can avoid such uncertainty.

Refer to caption
Figure S1: (a) Modified loops compared to the ones shown in the main text. In the trivial loop (left panel), we first fuse γB\gamma_{B} and γ1\gamma_{1} (FB1F_{B1}), followed by the splitting of γA\gamma_{A} and γB\gamma_{B} (FAB1F_{AB}^{-1}), and then reverse the operation to complete the loop. In the nontrivial loop (right panel), two consecutive processes do not commute with each other. (b) The charge transfer for the nontrivial loop FB1FAB1FABFB11F_{B1}F_{AB}^{-1}F_{AB}F_{B1}^{-1}. Here FAB1F_{AB}^{-1} (FABF_{AB}) is controlled by Ed(t)=E0[a±cos(ωt)]E_{d}(t)=E_{0}[a\pm\cos(\omega t)] with ω=1/1000 mev\omega=1/1000\text{ mev} and EM=109 mevE_{M}=10^{-9}\text{ mev}. After the splitting process, the energy level of the FM reaches exactly to zero for a=1a=1, stays above zero for a=1.1a=1.1, and changes sign for a=0.9a=0.9. (c) The charge transfer for the the trivial loop FB1FAB1FABFB11F_{B1}F_{AB}^{-1}F_{AB}F_{B1}^{-1}. (d) and (e) show the evolution of system parameters corresponding to (b) and (c), respectively.

Moreover, the initial conditional for Ed>0E_{d}>0 and Ed<0E_{d}<0 is very important for the whole fusion process. Since we set the initial state composed by MZMs γ1\gamma_{1} and γ2\gamma_{2} as |012|0_{12}\rangle, the parity of the whole system would be completely determined by the initial sign of EdE_{d}. If Ed>0E_{d}>0, the initial state is |0AB012|0_{\text{AB}}0_{12}\rangle which means both the FM and MZMs are unoccupied, and the system is in even-parity state during the loop. If Ed<0E_{d}<0, however, the initial state would be |1AB012|1_{\text{AB}}0_{12}\rangle which means FM is occupied and MZM is unoccupied with the total parity being odd. Figure S2(a) reveals the evolution of wavefunction ψ12+(t)\psi_{12}^{+}(t) in the nontrivial fusion loop. Here ψ12+(t)\psi_{12}^{+}(t) is the evolution state of ψ12+(0)\psi_{12}^{+}(0) at time tt, and ψAB±(0)=γA±iγB\psi_{AB}^{\pm}(0)=\gamma_{A}\pm i\gamma_{B}, ψ12±(0)=γ1±iγ2\psi_{12}^{\pm}(0)=\gamma_{1}\pm i\gamma_{2}. As we can see, ψ12+(t)\psi_{12}^{+}(t) would transform as ψ12(0)\psi_{12}^{-}(0) after the whole fusion loop. This means the initial state is |0AB012|0_{\text{AB}}0_{12}\rangle, and it would gradually switch to state |1AB112|1_{\text{AB}}1_{12}\rangle after a complete loop. During the evolution, an integer charge would be pumped to FM. The pumping is accomplished through TH process. This is consistent with the current plot in Fig. S2(c). In the whole process, Je(t)J_{e}(t), the current induced by TE process, remains to be zero, while Jh(t)J_{h}(t), the current induced by TH process, takes finite value. Figure S2(b) reveals the evolution of wavefunction ψ12+(t)\psi_{12}^{+}(t) in the situation Ed<0E_{d}<0, where the initial state is |1AB012|1_{\text{AB}}0_{12}\rangle, and gradually switches to state |0AB112|0_{\text{AB}}1_{12}\rangle in the end of the loop. The corresponding pumping is accomplished through TE process as shown in Fig. S2(d).

Refer to caption
Figure S2: The charge transfer and the evolution of the wavefunction ψB1+(t)\psi_{B1}^{+}(t) following the loop FB1FAB1FABFB11F_{B1}F_{AB}^{-1}F_{AB}F_{B1}^{-1} with the initial state Ed(0)>0E_{d}(0)>0 in (a) and Ed(0)<0E_{d}(0)<0 in (b). Here the fusion (FABF_{AB}) and splitting process (FAB1F_{AB}^{-1}) is controlled by Ed(t)=E0[a±cos(ωt)]E_{d}(t)=E_{0}[a\pm\cos(\omega t)] with a=0a=0. E0E_{0} is a positive value in (a) and a negative value in (b). The other parameters are the same as Fig. S1. Although the evolution of wavefunction are the same in both situations, they choose different transfer process. The transfer process in (a) is TH process as shown in (c) since the parity of initial state is even for Ed(0)>0E_{d}(0)>0, while the transfer process in (b) is TE process as shown in (d) since the parity of initial state is odd for Ed(0)<0E_{d}(0)<0.

Appendix B Reduced step for nontrivial fusion

Since the charge pumping is determined by the number of intersections of Ed(t)E_{d}(t) and tc(t)t_{c}(t) at zero energy, we can then control the pumping charge by adjusting both the fusion and splitting steps, as illustrated in Fig. S3(a). For the trivial loop, EdE_{d} and tct_{c} can be modulated at the same time as Ed=E0cos(ωt+ϕ02)E_{d}=E_{0}\cos(\frac{\omega t+\phi_{0}}{2}), tc=|E0|[1cos(ωt+ϕ0)]/2t_{c}=|E_{0}|[1-\cos(\omega t+\phi_{0})]/2. In this situation, the fusion loop can be reduced to two steps. For the nontrivial case as shown in Fig. S3(b), the first two steps of FAB1F_{AB}^{-1} and FB1F_{B1} are gated individually and the other two steps can be adjusted at the same time. To be specific, we set tc=0t_{c}=0 and Ed(t)=E0[a+cos(ωt)]E_{d}(t)=E_{0}[a+\cos(\omega t)] in the first step with ωt[0,π]\omega t\in[0,\pi], then tc(t)=|E0|[1+cos(ωt)]/2t_{c}(t)=|E_{0}|[1+\cos(\omega t)]/2 for ωt[π,2π]\omega t\in[\pi,2\pi], and finally the splitting and fusion processes can be realized at the same time by setting Ed(t)=E0[acos(ωt)]E_{d}(t)=E_{0}[a-\cos(\omega t)] and tc(t)=|E0|[1+cos(ωt)]/2t_{c}(t)=|E_{0}|[1+\cos(\omega t)]/2 for ωt[2π,3π]\omega t\in[2\pi,3\pi]. Clearly, the charge transfer displays the same behavior as when we manipulate each step individually in the main text. In the case of a=1a=1, which means EdE_{d} is tuned exactly to zero energy after the first step as shown by the dashed line in Fig. S3(d), the system would have no definite way to evolve in the subsequent step. As we increase tct_{c} to be tcEd0t_{c}\gg E_{d}\approx 0, the system would be in a superposition state of |0AB012|0_{\text{AB}}0_{12}\rangle and |1AB112|1_{\text{AB}}1_{12}\rangle. After the couplings recover the initial values through the final step, such a nontrivial fusion process would introduce a half charge transfer, as revealed by the dashed line in Fig. S3(b). A small deviation with a=1.05a=1.05 would result in zero charge transfer as revealed by the red dotted line shown in Fig. S3(b) (The corresponding Ed(t)E_{d}(t) is shown by the red dotted line in Fig. S3(d)). However, if a=0.95a=0.95, the energy of FM would change sign and the system chooses |1AB112|1_{\text{AB}}1_{12}\rangle, resulting in an integer charge transferred from FM to MZMs after one period as black solid line in Fig. S3(b) shows.

Refer to caption
Figure S3: (a) Path 1 represents the trivial fusion loop with only two steps and path 2 is the non-trivial fusion loop with three steps. For path 2, we set the parameters as Ed(t)=E0[a+cos(ωt)]E_{d}(t)=E_{0}[a+\cos(\omega t)] for ωt[0,π]\omega t\in[0,\pi], then tc(t)=|E0|[1+cos(ωt)]/2t_{c}(t)=|E_{0}|[1+\cos(\omega t)]/2 for ωt[π,2π]\omega t\in[\pi,2\pi], and finally Ed(t)=E0[acos(ωt)]E_{d}(t)=E_{0}[a-\cos(\omega t)] and tc(t)=|E0|[1+cos(ωt)]/2t_{c}(t)=|E_{0}|[1+\cos(\omega t)]/2 for ωt[2π,3π]\omega t\in[2\pi,3\pi]. (b) Charge transfer at a=1.05a=1.05, 11, and 0.950.95 with E0=0.1 evE_{0}=0.1\text{ ev}. Since the charge chooses different fusion channel for a>1a>1 and a<1a<1, the final charge transfer is different (zero for a>1a>1 and one for a<1a<1). (c) The charge transfer for E0=0.1 evE_{0}=-0.1\text{ ev}. The current following direction is reverse. (d) and (e) show the correspond manipulation of EdE_{d} and tct_{c} in (b) and (c), respectively.

The charge transfer would be more stable with a slowly period. As further revealed in Fig. S4(a), for an initial state |0AB012|0_{\text{AB}}0_{12}\rangle, EdE_{d} would cross zero for a<1a<1 after the first step, then the states would transfer to |1AB112|1_{\text{AB}}1_{12}\rangle state, which would cause an integer charge pumping from MZM to FM. If a>1a>1, EdE_{d} would remain above zero energy all the time, then the states would transfer back to |0AB012|0_{\text{AB}}0_{12}\rangle, with no net charge transfer in the end. We investigate the charge transfer process for different period T=104(eV)1T=10^{4}(eV)^{-1}, T=0.5104(eV)1T=0.5*10^{4}(eV)^{-1}, T=103(eV)1T=10^{3}(eV)^{-1} with ωT=π\omega T=\pi. We can see that the charge pumping δNF\delta N_{F} after the manipulation is definite with slowly oscillation period. Since we keep tct_{c} at zero in the first step as EdE_{d} varies, we further study the case for tc0t_{c}\neq 0. We investigate the parameters varying as Ed(t)=E0[a+cos(ωt)]E_{d}(t)=E_{0}[a+\cos(\omega t)] and tc(t)=|E0|[1cos(ϕ0)]/2t_{c}(t)=|E_{0}|[1-\cos(\phi_{0})]/2 for ωt[0,π]\omega t\in[0,\pi], then tc(t)=|E0|[1cos(ωt+ϕ0)]/2t_{c}(t)=|E_{0}|[1-\cos(\omega t+\phi_{0})]/2 for ωt[π,2π]\omega t\in[\pi,2\pi], and finally Ed(t)=E0[acos(ωt)]E_{d}(t)=E_{0}[a-\cos(\omega t)] and tc(t)=|E0|[1+cos(ωt+ϕ0)]/2t_{c}(t)=|E_{0}|[1+\cos(\omega t+\phi_{0})]/2 for ωt[2π,3π]\omega t\in[2\pi,3\pi]. It is the same as the parameters of Fig. 4 in the main text except that there’s an initial deviation ϕ0\phi_{0} in tct_{c}. We show the final charge transfer versus period TT at a=0.9a=0.9 in Fig. S4(b). We find that the nontrivial charge transfer can still be distinguished even for ϕ0=0.05π\phi_{0}=0.05\pi for T[103,104](eV)1T\in[10^{3},10^{4}](eV)^{-1}. This suggests that the nontrivial pumping to be observed when the time period T1/min(tc)T\ll 1/\min(t_{c}), where min(tc)\min(t_{c}) represents the minimum value of tct_{c} at the moment of intersection. Moreover, adiabatic evolution further requires T1/ΔT\gg 1/\Delta. As a result, the time window for the nontrivial pumping is 1/ΔT1/min(tc)1/\Delta\ll T\ll 1/\min(t_{c}).

Refer to caption
Figure S4: (a) The charge transfer is distinct for a>1a>1 and a<1a<1 with different time period. There’s an integer charge transfer if a<1a<1, and no charge transfer if a>1a>1. Since such process is an adiabatic process, the transition region would become more and more steep with time increase. (b) The influence of final charge transfer in the case of tc0t_{c}\neq 0. We set tc(t)=|E0|(1cos(ϕ0))/2t_{c}(t)=|E_{0}|(1-\cos(\phi_{0}))/2 in the initial time. This means tc0t_{c}\neq 0 for ϕ00\phi_{0}\neq 0, It would gradually destroy nontrivial charge transfer process but still sustains in a finite time window

Appendix C The Hamiltonian and parameters for tight-binding model

The tight binding Hamiltonian of the NS system is given by

HNS\displaystyle H_{NS} =\displaystyle= 𝐑,𝐝,αt0(ψ𝐑+𝐝,αψ𝐑,α+h.c.)μψ𝐑,αψ𝐑,α\displaystyle\sum\nolimits_{\mathbf{R},\mathbf{d},\alpha}{-t_{0}(\psi_{\mathbf{R}+\mathbf{d},\alpha}^{\dagger}\psi_{\mathbf{R},\alpha}+h.c.)-\mu\psi_{\mathbf{R},\alpha}^{\dagger}\psi_{\mathbf{R},\alpha}} (S1)
+\displaystyle+ 𝐑,𝐝,α,βiURψ𝐑+𝐝,αz^(σ×𝐝)αβψ𝐑,β\displaystyle\sum\nolimits_{\mathbf{R},\mathbf{d},\alpha,\beta}{-i{U_{R}}\psi_{\mathbf{R}+\mathbf{d},\alpha}^{\dagger}\hat{z}\cdot(\vec{\sigma}\times\mathbf{d})_{\alpha\beta}\psi_{\mathbf{R},\beta}}
+\displaystyle+ 𝐑,αΔ(R)eiϕψ𝐑,αψ𝐑,α+h.c.\displaystyle\sum\nolimits_{\mathbf{R},\alpha}\Delta(R)e^{i\phi}\psi_{\mathbf{R},\alpha}^{\dagger}\psi_{\mathbf{R},-\alpha}^{\dagger}+h.c.
+\displaystyle+ 𝐑,α,βψ𝐑,α(Vxσx)αβψ𝐑,β.\displaystyle\sum\nolimits_{\mathbf{R},\alpha,\beta}{\psi_{\mathbf{R},\alpha}^{\dagger}(V_{x}\vec{\sigma}_{x})_{\alpha\beta}\psi_{\mathbf{R},\beta}}.

Here, the subscript 𝐑\mathbf{R} denotes the lattice site; 𝐝\mathbf{d} is the unit vector and 𝐝x\mathbf{d}_{x} connects the nearest neighbor sites along xx- direction; α\alpha and β\beta are the spin indices; t0t_{0} denotes the hopping amplitude; μ\mu is the chemical potential; URU_{R} is the Rashba coupling strength; and VxV_{x} is the Zeeman energy. The superconducting pairing amplitude is denoted as Δ\Delta, and ϕ\phi is the pairing phase. In the numerical simulations, the effective mass m=0.026mem^{*}=0.026m_{e}, the Rashba spin-orbit coupling strength α=30 mevnm\alpha=30\text{ mev}\cdot\text{nm}, the superconducting pairing strength Δ=0.25 mev\Delta=0.25\text{ mev}, the g factor g=15g=15, the length of nanowire is Nx=120aN_{x}=120a with he lattice constant a=20 nma=20\text{ nm}, The quantum dot which connects with the nanowire is described by

Hd=α2Eddαdα+α,βdα(Vxσx)αβdβ,H_{d}=\sum\nolimits_{\alpha}2E_{d}d^{\dagger}_{\alpha}d_{\alpha}+\sum\nolimits_{\alpha,\beta}{d_{\alpha}^{\dagger}(V_{x}\vec{\sigma}_{x})_{\alpha\beta}d_{\beta}}, (S2)

where EdE_{d} represents the on-site energy of the QD and dαd_{\alpha} is the fermionic annihilation operator with spin α\alpha. The coupling between the nanowire and the QD is described by the hopping term

HSd=αtcψ1,Nx,αdα+h.c.,H_{Sd}=\sum\nolimits_{\alpha}t_{c}\psi^{\dagger}_{1,N_{x},\alpha}d_{\alpha}+h.c., (S3)

where tct_{c} is the coupling strength.

In experiment, the trivial Andreev bound states (ABSs) could appear at zero energy and blend with MZMs. It is necessary to investigate the fusion rule of trivial ABSs. Such ABS is usually induced by a hard-wall confined potential at the interface, which can be modeled by a square quantum well confinement at the end of the nanowire Marcus ; Aguado ; ChunXiao1 . We simulate the square quantum well by setting μ(R)=2t\mu(R)=-2t, Δ(R)=0\Delta(R)=0 for 𝐑<20a\mathbf{R}<20a and μ(R)=2t+0.45 mev\mu(R)=-2t+0.45\text{ mev} , Δ(R)=Δ\Delta(R)=\Delta for 𝐑>20a\mathbf{R}>20a. When an external magnetic field Vx1V_{x1} and a smooth confinement is applied in the nanowire, as shown in Fig. 4(b) of main text, ABS will be trapped in the confinement region before the topological phase transition occurs (0.2 mev<Vx1<0.45 mev0.2\text{ mev}<V_{x1}<0.45\text{ mev}). In contrast to the MZMs that distribute non-locally at both ends of the nanowire, the quasi-MZM can be viewed as two strongly overlapped MZMs γ1\gamma_{1} and γ2\gamma_{2} which are both localized inside the confinement region. To numerically simulate the fusion process in a NS wire, we follow the traditional time-evolution method of trotter decomposition Lei .

Appendix D Exact solution of FM-MZM hybrid system

In the main text we have shown a simple criterion for nontrivial charge pumping: if Ed(t)E_{d}(t) and tc(t)t_{c}(t) intersect at zero energy an odd number of times, the charge pumping becomes nontrivial, and the opposite is true for even intersections. Such rule is different from Thouless pumping. In Thouless pumping, the charge pumping is determined by the winding number encircled by the parameters. However, we can still find a exact solution for this system. We start with the Hamiltonian HMH_{M} in the Majorana representation, given by:

HM\displaystyle H_{M} =iEdγAγB+i|tc|γBγ1.\displaystyle=i{E_{d}}\gamma_{A}\gamma_{B}+i|t_{c}|\gamma_{B}{\gamma_{1}}. (S4)

In the qubit operator representation: σz=iγAγB\sigma_{z}=i\gamma_{A}\gamma_{B} and σx=iγBγ1\sigma_{x}=i\gamma_{B}\gamma_{1}, and the Hamiltonian exactly describes a typical two-level system. Since σz\sigma_{z} and σx\sigma_{x} do not commute with each other, tuning EdE_{d} and tct_{c} in different order would lead to distinct results. However, since the charge pumping only depends on the intersections of system parameters during the evolution in a complete loop, we do not have to care about the specific forms of the paths such as the form of Ed(t)E_{d}(t) or tc(t)t_{c}(t). The nontrivial loop can thus be homotopy to a loop with two periods: in the first period, we vary EdE_{d} from E0E_{0} to E0-E_{0} while tct_{c} keeps zero. In the second part, we set Ed=E0cos(ωt)E_{d}=-E_{0}\cos(\omega t) and tc=E0sin(ωt)t_{c}=E_{0}\sin(\omega t) from ωt=0\omega t=0 to ωt=π\omega t=\pi. This is just a half circle in the parameter space. For the first part, the evolution would induce a dynamical phase ϕ=0TEd(t)σz𝑑t\phi=\int_{0}^{T}E_{d}(t)\sigma_{z}dt. While for the second part, it is just a nuclear magnetic resonance system with HN(t)=E0cos(ωt)σz+E0sin(ωt)σxH_{N}(t)=-E_{0}\cos(\omega t)\sigma_{z}+E_{0}\sin(\omega t)\sigma_{x}. This Hamiltonian can be exactly calculated through unitary transformation U^(t)=exp(iωt2σy)\hat{U}(t)=\exp(-i\frac{\omega t}{2}\sigma_{y}). Then the effective Hamiltonian would become time independent:

Heff=U^(t)HN(t)U^(t)1U^(t)(itU^(t)1)=E0σzω2σy.\displaystyle H_{eff}=\hat{U}(t)H_{N}(t)\hat{U}(t)^{-1}-\hat{U}(t)(-i\frac{\partial}{\partial t}\hat{U}(t)^{-1})=-E_{0}\sigma_{z}-\frac{\omega}{2}\sigma_{y}. (S5)

Now the time evolution operator UU can be given by:

U(t)=U^(t)eiHefft=exp(iωt2σy)[cos(Ωt)isin(Ωt)(E0Ωσzω2Ωσy)]\displaystyle U(t)=\hat{U}(t)e^{-iH_{eff}t}=\exp(-i\frac{\omega t}{2}\sigma_{y})[\cos(\Omega t)-i\sin(\Omega t)(\frac{E_{0}}{\Omega}\sigma_{z}-\frac{\omega}{2\Omega}\sigma_{y})] (S6)

Here, Ω=E02+(ω/2)2\Omega=\sqrt{E_{0}^{2}+(\omega/2)^{2}}. If ωE0\omega\ll E_{0}, then ΩE0\Omega\simeq E_{0} and U(t)exp(iωt2σy)exp(iE0tσz)U(t)\simeq\exp(-i\frac{\omega t}{2}\sigma_{y})\exp(iE_{0}t\sigma_{z}). In this situation, the states would be slowly rotated with frequency ω/2\omega/2. Then the state would change from |0AB012|0_{\text{AB}}0_{12}\rangle to |1AB112|1_{\text{AB}}1_{12}\rangle in the end of the loop.

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