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Tunneling conductance of d+ipd+ip -wave superconductor

Yuhi Takabatake    Shu-Ichiro Suzuki [email protected]    Yukio Tanaka Department of Applied Physics, Nagoya University, Nagoya 464-8603, Japan
Abstract

We theoretically investigate the tunneling conductance of the d+ipd+ip-wave superconductor that has recently been proposed to be realized at the (110) surface of a high-TcT_{c} cuprate superconductor. Utilizing the quasiclassical Eilenberger theory, we obtain the self-consistent pair potentials and the differential conductance of the normal-metal/d+ipd+ip-wave superconductor junction. We demonstrate that the zero-bias peak of a dd-wave superconductor is robust against the spin-triplet pp-wave surface subdominant order, even though it is fragile against the spin-singlet ss-wave one. Comparing our numerical results with experimental results, we conclude that the spin-triplet pp-wave surface subdominant order is feasible.

preprint: APS/123-QED

I Introduction

Refer to caption
Figure 1: Schematic of the normal-metal (N)/ superconductor (S) junction. The dxyd_{xy}-wave superconductor that corresponds to the (110) of a cuprate superconductor is realized in S. Because of the flat-band instability, a subdominant pair potential is induced near the interface. There is a barrier potential ZZ at the interface.

Unconventional superconductors (SCs) can host surface bound states, the Andreev bound states (ABSs), forming a zero-energy flat band Buchholtz and Zwicknagl (1981); Hara and Nagai (1986); Hu (1994); Matsumoto and Shiba (1995a); Kashiwaya and Tanaka (2000); Löfwander et al. (2001). The zero-energy ABSs can be observed as a zero-bias conductance peak (ZBCP) in the quasiparticle tunneling spectra of the junctions of a normal metal and a high-TcT_{c} cuprate (i.e., a spin-singlet dd-wave SC) Tanaka and Kashiwaya (1995); Kashiwaya et al. (1995a, 1998); Covington et al. (1997); Alff et al. (1997); Wei et al. (1998); Biswas et al. (2002); Chesca et al. (2008); Bouscher et al. (2020); Saadaoui et al. (2013). In addition, the ABSs induce a Josephson current with a low-temperature anomaly Tanaka and Kashiwaya (1996, 1997); Barash et al. (1996) and a paramagnetic Meissner current Higashitani (1997); Barash et al. (2000); Tanaka et al. (2005); Asano et al. (2011); Yokoyama et al. (2011); Suzuki and Asano (2014); Higashitani (2014); Suzuki and Asano (2015); Espedal et al. (2016); Lee et al. (2017). The origin of the ABSs has been clarified from the view point of the topological invariant defined using the bulk Hamiltonian Sato et al. (2011).

The zero-energy ABSs may be fragile against perturbations because of the high degeneracy of the flat band. The surface ss-wave subdominant order originating this instability was proposed Matsumoto and Shiba (1995b); Kuboki and Sigrist (1996) in 1995. Theoretically, the subdominant ss-wave component splits the zero-energy peak in the local density of states (LDOS) Kashiwaya et al. (1995b); Tanuma et al. (1999, 2001a) and gives rise to a spontaneous surface current by breaking the time reversal symmetry (TRS) Matsumoto and Shiba (1995c). In experiments, however, neither such peak splitting nor TRS breaking has been observed Kashiwaya et al. (1995a, 1998); Alff et al. (1997); Wei et al. (1998); Biswas et al. (2002); Chesca et al. (2008); Bouscher et al. (2020); Saadaoui et al. (2013), except for a few cases Covington et al. (1997); Fogelström et al. (1997); Krupke and Deutscher (1999). More seriously, the induced ss-wave pair potential requires an on-site attractive interaction, in contradiction to the strong repulsive interaction in the cuprate. The instability of the ABSs is not still conclusive, even though other possibilities have been pointed out, such as surface ferromagnetism Potter and Lee (2014), spin density wave Honerkamp and Sigrist (1998), staggered flux phase Kuboki (2014, 2015), and translational symmetry breaking Vorontsov (2009); Higashitani and Miyawaki (2015); Miyawaki and Higashitani (2015, 2017); Håkansson et al. (2015); Holmvall et al. (2018); Miyawaki and Higashitani (2018); Holmvall et al. (2019).

The spin-triplet pp-wave subdominant order has recently been proposed using the finite-size two-dimensional Hubbard model with the random-phase approximation Matsubara and Kontani (2020a). The ferromagnetic fluctuation caused by the ABSs can stabilize such a pp-wave subdominant order, which breaks the TRS Matsubara and Kontani (2020b). The obtained d+ipd+ip-wave pairing shows different properties compared with those of the d+isd+is-wave: there is no clear zero-energy splitting in the LDOS and no spontaneous surface current. Although a number of papers have studied the d+isd+is-wave state Matsumoto and Shiba (1995b, c); Tanuma et al. (1999, 2001a), the unique properties of the d+ipd+ip-wave state have not yet been clarified. In particular, the mixture of the spin-singlet and spin-triplet pairs would cause non-trivial phenomena.

We here study the conductance spectra of the normal-metal/dxyd_{xy}-wave SC junctions with a subdominant pyp_{y}-wave pair potential at the interface and compare the results with those for the well-known d+isd+is-wave superconducting junction. We consider a ballistic planar junction, as shown in Fig. 1, where the barrier potential is present at the interface. Utilizing the quasiclassical Eilenberger formalism, we obtain the differential conductance using the pair potential obtained by solving the self-consistency equation. The calculated results show that the ZBCP of the dxyd_{xy}-wave SC can survive under the spin-triplet pyp_{y}-wave subdominant pair potential, even though it is fragile against the spin-singlet ss-wave subdominant pair potential. From the spin-resolved conductance spectra, we show that the transport properties of the d+ipd+ip-wave junction strongly depend on the spin of an injected electron because of the coexistence of the spin-triplet and singlet pairs near the interface.

We also investigate whether the ZBCP can survive, even if the pp-wave surface attractive potential is short-range and strong, as pointed out in Ref. Matsubara and Kontani, 2020a. The ZBCP is demonstrated to be robust even against such a short-range attractive potential. Comparing our results with experimental data, we conclude that our results, which take the subdominant pp-wave order into account phenomenologically, support recent theoretical predictions based on microscopic calculations.

II Model and formulation

We consider the ballistic normal-metal/dxyd_{xy}-wave SC junction shown in Fig. 1, where the SC and the normal-metal (N) occupy x0x\geq 0 and x<0x<0 respectively. In a ballistic SC, Green’s function obeys the Eilenberger equation Eilenberger (1968):

ivFxxgˇαα=α[iωnτˇ3+Δˇα,gˇαα],\displaystyle iv_{F_{x}}\partial_{x}\check{g}_{\alpha\alpha}=-\alpha[i\omega_{n}\check{\tau}_{3}+\check{\Delta}_{\alpha},\check{g}_{\alpha\alpha}], (1)
gˇαα(ϕ,x,iωn)=[g^ααf^ααf~^ααg~^αα]\displaystyle\check{g}_{\alpha\alpha}(\phi,x,i\omega_{n})=\left[\begin{array}[]{rr}\hat{g}_{\alpha\alpha}&\hat{f}_{\alpha\alpha}\\ -\hat{\undertilde{f}}_{\alpha\alpha}&-\hat{\undertilde{g}}_{\alpha\alpha}\end{array}\right] (4)

where g^\hat{g} and f^\hat{f} are the normal and anomalous Green’s functions, vFxv_{F_{x}} is the xx component of the Fermi velocity vFv_{F}, ωn\omega_{n} is the Matsubara frequency with the integer nn, the direction of the momentum is characterized by the angle ϕ\phi (kx=αcosϕk_{x}=\alpha\cos\phi, and ky=sinϕk_{y}=\sin\phi with α=±1\alpha=\pm 1 and π/2ϕπ/2-\pi/2\leq\phi\leq\pi/2), Δˇα=Δˇα(ϕ,x)\check{\Delta}_{\alpha}=\check{\Delta}_{\alpha}(\phi,x), and τˇj\check{\tau}_{j} (j=1j=1, 22, or 33) are the Pauli matrices in the particle-hole space. In this study, the symbols ˇ\check{\cdot} and ^\hat{\cdot} denotes the matrices in the particle–hole and spin space, respectively. The pair-potential matrix is defined as

Δˇα=[Δ^Δ^],Δ^=[ΔΔ],\displaystyle\check{\Delta}_{\alpha}=\left[\begin{array}[]{cc}&\hat{\Delta}\\ -\hat{\Delta}^{\dagger}&\end{array}\right],\hskip 17.07164pt\hat{\Delta}=\left[\begin{array}[]{cc}&\Delta_{\uparrow\downarrow}\\ \Delta_{\downarrow\uparrow}&\end{array}\right], (9)

where we have omitted the index α\alpha. The spin structure of the pair potential is parametrized as

Δ^={Δd(iσ^2)+iΔpσ^1for d+ip wave, (Δd+iΔs)iσ^2for d+is wave, \displaystyle\hat{\Delta}=\left\{\begin{array}[]{cc}\Delta_{d}(i\hat{\sigma}_{2})+i\Delta_{p}\hat{\sigma}_{1}&\text{for $d+ip$ wave, }\\[5.69054pt] (\Delta_{d}+i\Delta_{s})i\hat{\sigma}_{2}&\text{for $d+is$ wave, }\end{array}\right. (12)

where Δμ\Delta_{\mu} (μ=s\mu=s, pp, and dd) is the amplitude of the μ\mu-wave pair potential and σ^j\hat{\sigma}_{j} (j=1j=1, 22, or 33) are the Pauli matrices in spin space. The momentum dependence of the pair potentials are given by

Δd(x,ϕ)=\displaystyle\Delta_{d}(x,\phi)= Δd(x)sin(2ϕ),\displaystyle\Delta_{d}(x)\sin(2\phi), (13)
Δp(x,ϕ)=\displaystyle\Delta_{p}(x,\phi)= Δp(x)sinϕ,\displaystyle\Delta_{p}(x)\sin\phi, (14)
Δs(x,ϕ)=\displaystyle\Delta_{s}(x,\phi)= Δs(x).\displaystyle\Delta_{s}(x). (15)

The pair potentials are determined by the self-consistency equation:

Δμ=Λμn=0ncTr[V^μ(ϕ)f^αα(ϕ,x,iωn)]FS,\displaystyle\Delta_{\mu}=\Lambda_{\mu}\sum_{n=0}^{n_{c}}\left\langle\mathrm{Tr}[\hat{V}_{\mu}(\phi)\hat{f}_{\alpha\alpha}(\phi,x,i\omega_{n})]\right\rangle_{\mathrm{FS}}, (16)

where the angular brackets means the angle average on the Fermi surface: =απ/2π/2(dϕ/2π)\langle\cdots\rangle=\sum_{\alpha}\int_{-\pi/2}^{\pi/2}\cdots({d\phi}/{2\pi}) and ncn_{c} is the cutoff integer which is decided by the relation 2nc+1<ωc/πT2nc+32n_{c}+1<\omega_{c}/\pi T\leq 2n_{c}+3 with ωc\omega_{c} being the cutoff energy. The attractive potential depends on the pairing symmetry:

V^μ(ϕ)={2iσ^2sin(2ϕ)for the d wave, 2σ^1sinϕfor p wave, iσ^2for s wave. \displaystyle\hat{V}_{\mu}(\phi)=\left\{\begin{array}[]{ll}2i\hat{\sigma}_{2}\sin(2\phi)&\text{for the $d$ wave, }\\[5.69054pt] 2\hat{\sigma}_{1}\sin\phi&\text{for $p$ wave, }\\[5.69054pt] i\hat{\sigma}_{2}&\text{for $s$ wave. }\end{array}\right. (20)

The coupling constant Λμ\Lambda_{\mu} is

Λμ=2πT[ln(TTμ)+n=0nc1n+1/2]1,\displaystyle\Lambda_{\mu}=2\pi T\left[\ln\left(\frac{T}{T_{\mu}}\right)+\sum_{n=0}^{n_{c}}\frac{1}{n+{1}/{2}}\right]^{-1}, (21)

where TμT_{\mu} is the effective critical temperature. Namely, the ratio Tp/TdT_{p}/T_{d} and Ts/TdT_{s}/T_{d} characterize the amplitude of the subdominant pair potential.

The microscopic theoriesMatsubara and Kontani (2020a, b) suggest that the attractive potential for the pp-wave channel may be short-range. To model such a short-range potential, we introduce the spatial-dependent attractive potential Λμ(x)\Lambda_{\mu}^{\prime}(x) as

Λμ(x)=Λμexp[x/κ],\displaystyle\Lambda_{\mu}^{\prime}(x)=\Lambda_{\mu}\exp\left[-x/\kappa\right], (22)

where κ\kappa is the decay parameter which characterizes the length scale of the attractive potential. Replacing Λμ\Lambda_{\mu} in Eq. (16) by Λμ(x)\Lambda_{\mu}^{\prime}(x), we can self-consistently calculate the subdominant pair potential under the short-range attractive potential.

When the pair-potential matrix does not have the diagonal component as in Eq. (12), the 4×44\times 4 Eilenberger equation can be decomposed into two 2×22\times 2 ones:

ivFxxg~ααX=α[iωnτ~3+Δ~αX,g~ααX].\displaystyle iv_{F_{x}}\partial_{x}\tilde{g}^{X}_{\alpha\alpha}=-\alpha[i\omega_{n}\tilde{\tau}_{3}+\tilde{\Delta}^{X}_{\alpha},\tilde{g}^{X}_{\alpha\alpha}]. (23)

The spin-reduced Green’s function g~X\tilde{g}^{X} and the pair potential are defined as

g~O=[gff~g~],g~I=[gff~g~],\displaystyle\tilde{g}^{O}=\left[\begin{array}[]{cc}g_{\uparrow}&f_{\uparrow\downarrow}\\ -\undertilde{f}_{\downarrow\uparrow}&-\undertilde{g}_{\downarrow}\end{array}\right],\hskip 14.22636pt\tilde{g}^{I}=\left[\begin{array}[]{cc}g_{\downarrow}&f_{\downarrow\uparrow}\\ -\undertilde{f}_{\uparrow\downarrow}&-\undertilde{g}_{\uparrow}\end{array}\right], (28)
Δ~αO=[ΔΔ],Δ~αI=[ΔΔ].\displaystyle\tilde{\Delta}_{\alpha}^{O}=\left[\begin{array}[]{cc}&\Delta_{\uparrow\downarrow}\\ -\Delta^{*}_{\uparrow\downarrow}&\end{array}\right],\hskip 8.53581pt\tilde{\Delta}_{\alpha}^{I}=\left[\begin{array}[]{cc}&\Delta_{\downarrow\uparrow}\\ -\Delta^{*}_{\downarrow\uparrow}&\end{array}\right]. (33)

where we omit the direction index α\alpha and the index X=OX=O and II means the outer and inner components in the Nambu space respectively. Hereafter we make the index XX explicit only when necessary. Using the Riccati parametrization Schopohl and Maki (1995); Eschrig (2000, 2009), the quasiclassical Green’s functions g^ααX\hat{g}^{X}_{\alpha\alpha} can be expressed as

g~αα=i1DαFα(1+DαFα2iαFα2iαDα(1+DαFα))\displaystyle\tilde{g}_{\alpha\alpha}=\frac{i}{1-D_{\alpha}F_{\alpha}}\left(\begin{array}[]{cc}1+D_{\alpha}F_{\alpha}&2i\alpha F_{\alpha}\\[2.84526pt] 2i\alpha D_{\alpha}&-(1+D_{\alpha}F_{\alpha})\end{array}\right) (36)

where Dα=DαXD_{\alpha}=D_{\alpha}^{X} and Fα=FαXF_{\alpha}=F_{\alpha}^{X} are the so-called Riccati amplitudes. The Riccati amplitudes obey the following Riccati-type differential equations:

vFxxD+=2ωnD++Δ+D+2Δ+,\displaystyle v_{F_{x}}\partial_{x}D_{+}=2\omega_{n}D_{+}+\Delta_{+}D^{2}_{+}-\Delta^{*}_{+}, (37)
vFxxD=2ωnD+ΔD2Δ,\displaystyle v_{F_{x}}\partial_{x}D_{-}=2\omega_{n}D_{-}+\Delta^{*}_{-}D^{2}_{-}-\Delta_{-}, (38)
vFxxF+=2ωnF++Δ+F+2Δ+,\displaystyle v_{F_{x}}\partial_{x}F_{+}=-2\omega_{n}F_{+}+\Delta^{*}_{+}F^{2}_{+}-\Delta_{+}, (39)
vFxxF=2ωnF+ΔF2Δ,\displaystyle v_{F_{x}}\partial_{x}F_{-}=-2\omega_{n}F_{-}+\Delta_{-}F^{2}_{-}-\Delta^{*}_{-}, (40)

The Eilenberger equation is supplemented by the boundary conditions Ashida et al. (1989); Nagato et al. (1993); Eschrig (2000); Tanuma et al. (2001b); Hirai et al. (2003); Eschrig (2009). The boundary conditions at the N/SC interface are given by:

F±(0)=RsωD(0),\displaystyle F_{\pm}(0)=-R^{s_{\omega}}D_{\mp}(0), (41)

where RR is the reflection probability amplitude and sω=sgn[ωn]s_{\omega}=\mathrm{sgn}[\omega_{n}].

II.1 Real-energy representation

In order to discuss the quantities depending on the energy, we need the Green’s function in the real-frequency representation. The Green’s function in the real-energy space can be obtained by the analytic continuation; iωnE+iδi\omega_{n}\to E+i\delta. In this case, the Riccati amplitudes are also converted as

D±X(x,iωn)=iΓ±X(x,E),F±X(x,iωn)=iζ±X(x,E).\displaystyle D_{\pm}^{X}(x,i\omega_{n})=i\Gamma^{X}_{\pm}(x,E),\quad F_{\pm}^{X}(x,i\omega_{n})=i\zeta^{X}_{\pm}(x,E). (42)

From the Riccati amplitude Γ±\Gamma_{\pm}, we can directly calculate the angle-resolved conductance as a function of E=eVE=eV and ϕ\phi:

σR=1+σN|Γ+|2+(σN1)|Γ+Γ|2|1+(σN1)Γ+Γ|2\displaystyle\sigma_{R}=\frac{1+\sigma_{N}|\Gamma_{+}|^{2}+(\sigma_{N}-1)|\Gamma_{+}\Gamma_{-}|^{2}}{|1+(\sigma_{N}-1)\Gamma_{+}\Gamma_{-}|^{2}} (43)

where Γ±=Γ±(x=0,E,ϕ)\Gamma_{\pm}=\Gamma_{\pm}(x=0,E,\phi), σR=σR(E,ϕ)\sigma_{R}=\sigma_{R}(E,\phi), σN=σN(ϕ)\sigma_{N}=\sigma_{N}(\phi), VV is the bias voltage applied to the junction and Γ±=Γ±X\Gamma_{\pm}=\Gamma_{\pm}^{X}. The conductance in the normal state is obtained by solving the scattering problem: σN(ϕ)=1R=cos2ϕ/(Z2+cos2ϕ)\sigma_{N}(\phi)=1-R={\cos^{2}\phi}/(Z^{2}+\cos^{2}\phi), where we assume the potential barrier ZvFδ(x)Zv_{F}\delta(x) with δ(x)\delta(x) being the delta function.

The total conductance is defined as

GNS(E)=Xπ/2π/2GNSX(E,ϕ)cosϕdϕ,\displaystyle G_{\mathrm{NS}}(E)=\sum_{X}\int^{\pi/2}_{-\pi/2}G_{\mathrm{NS}}^{\prime X}(E,\phi)\cos\phi d\phi, (44)
GNSX(E,ϕ)=σN(ϕ)σRX(E,ϕ).\displaystyle G_{\mathrm{NS}}^{\prime X}(E,\phi)=\sigma_{N}(\phi)\sigma^{X}_{R}(E,\phi). (45)

where GNSX(E,ϕ)G_{\mathrm{NS}}^{\prime X}(E,\phi) is the angle-resolved differential conductance. The conductances GNSO(E,ϕ)G_{\mathrm{NS}}^{\prime O}(E,\phi) and GNSI(E,ϕ)G_{\mathrm{NS}}^{\prime I}(E,\phi) correspond to those to up-spin and down-spin injections, respectively. It is convenient to introduce the normalized conductance G¯NS=GNS/GNN\bar{G}_{\mathrm{NS}}=G_{\mathrm{NS}}/G_{\mathrm{NN}} with GNN=2π/2π/2σNcosϕdϕG_{\mathrm{NN}}=2\int^{\pi/2}_{-\pi/2}\sigma_{N}\cos\phi d\phi.

The local density of states (LDOS) can be obtained from the quasiclassical Green’s function. The LDOS is given by

ρ=1ππ/2π/2ρ(ϕ)𝑑ϕ,ρ(ϕ)=12αTr[gˇαα].\displaystyle\rho=\frac{1}{\pi}\int_{-\pi/2}^{\pi/2}\rho^{\prime}(\phi){d\phi},\quad\rho^{\prime}(\phi)=\frac{1}{2}\sum_{\alpha}\mathrm{Tr}[\check{g}_{\alpha\alpha}]. (46)

In quasiclassical theory, the LDOS is normalized by its normal-state value.

III Results

III.1 Differential conductance

Refer to caption
Figure 2: Differential conductances of (a) d+ipd+ip- and (b) d+isd+is-wave junctions. The magnified figures are shown in (c) and (d). The ZBCP is not split by the pp-wave subdominant component but by the ss-wave one. The ZBCP is robust against the pp-wave subdominant pair potential but is fragile against the ss-wave one. The barrier potential is set to Z=3Z=3. The pair potential is determined self-consistently. The temperature and the cutoff energy are set to T=0.05TdT=0.05T_{d} and ωc=2πTd\omega_{c}=2\pi T_{d}.
Refer to caption
Figure 3: Injected-spin dependence of GNSG_{\mathrm{NS}} of d+ipd+ip -wave junction The injected particle is assumed to be (a) up and (b) down, respectively. The differential conductance of the d+ipd+ip -wave junction depends on the injected spin because the subdominant component is spin-triplet pairing. The parameters are set to the same values used in Fig. 2.
Refer to caption
Figure 4: Angle-resolved differential conductances of d+ipd+ip -wave junctions for (a) up- and (b) down-spin injection. Zero-energy flat band of a dd-wave SC becomes dispersive by a pp -wave subdominant pair potential. The dispersion of the bound states changed from a flat band to the V-shaped. The surface states around ϕ=0\phi=0 stay around zero energy because the pp -wave component is small around ϕ=0\phi=0. The effective critical temperatures for the subdominant components are set to Tp=Ts=0.25TdT_{p}=T_{s}=0.25T_{d} in (a), (b), and (c).

The differential conductance for the d+ipd+ip- and d+isd+is-wave junctions are shown in Figs. 2(a) and 2(b), respectively, where the magnified figures are shown in Figs. 2(c) and 2(d) and the pair potentials are determined self-consistently (see Appendix for details). Throughout this paper, the temperature and cutoff-energy are set to T=0.05TdT=0.05T_{d} and ωc=2πTd\omega_{c}=2\pi T_{d}. Figure 2 shows that the ZBCP is robust against the pp- wave subdominant component but fragile against the ss-wave component. In the d+ipd+ip case, the ZBCP survives even when Tp/Td=0.25T_{p}/T_{d}=0.25. With increasing Tp/TdT_{p}/T_{d}, the ZBCP becomes broader where the peak width is roughly characterized by TpT_{p}. When Tp/Td=0.25T_{p}/T_{d}=0.25, Two peaks seem to overlap at eV=0eV=0: sharper one and broader one. In the d+isd+is case, the ZBCP is fragile against the subdominant pair potential as shown in Fig. 2(b). In the presence of the ss-wave pair potential, the ZBCP is split into two peaks, where distance between two peaks are characterised by TsT_{s}. This result is consistent with Ref.Matsumoto and Shiba, 1995b, c.

We explain the origin of the sharp and narrow peaks for the d+ipd+ip -wave junction by analyzing the injected-spin dependence of GNSG_{\mathrm{NS}}. The conductance for the up-spin and down-spin injections are shown in Fig. 3(a) and 3(b), respectively, where the parameters are set to the same values used in Fig. 2. The center of the zero-energy peak for the up-spin (down-spin) injection shifts from E=0E=0 to a finite positive (negative) energy, where the peak becomes broader simultaneously. Although the peak center moves from the zero bias, the zero-energy conductance (GNS/GNN)|E=0(G_{\mathrm{NS}}/G_{\mathrm{NN}})|_{E=0} always has an amplitude larger than the unity independent of the injected spin. Therefore, the ZBCP of the total conductance [Fig. 2(a)] does not disappear but becomes thicker by the subdominant pp-wave order parameter. The spin-resolved conductance for the d+isd+is-wave junction (not shown) does not depend on the injected spin because both of the dd- and ss-wave pairs are spin singlet.

The angle-resolved differential conductance are shown in Fig. 4, where the pairing symmetry is assumed d+ipd+ip-wave in (a) and (b), d+isd+is-wave in (c), and pure dd-wave in (d). The injected spin is assumed up in Figs. 4(a), 4(c) 4(d), whereas down in Fig. 4(b), where the conductance for the d+isd+is- and pure dd-wave junctions does not depend on the injected spin. In the absence of a subdominant pair potential, the angle-resolved conductance GNS(ϕ)G_{\mathrm{NS}}^{\prime}(\phi) has a peak at the zero bias voltage (i.e., eV=0eV=0) independent of ky=kFsinϕk_{y}=k_{F}\sin\phi, [see Fig. 4(d)].

Refer to caption
Figure 5: Schematic of the pair potentials. The pyp_{y}-wave subdominant component has a small amplitude for the low-angle injection (ϕ0\phi\sim 0), where the amplitude of the ss-wave component is independent of the angle. Reflecting the pyp_{y}wave nature, the zero-energy conductance peak of the d+ipd+ip-wave superconductor does not split.

In the presence of the pp-wave subdominant component, the in-gap conductance peak changes from a flat band to the V [inverted V] shape for up-spin [down-spin] injection, as shown in Fig. 4(a) [Fig. 4(b)]. However, the in-gap peak around ϕ=0\phi=0 stay around eV=0eV=0 because the pp -wave component has nodes at ϕ=0\phi=0 (see Fig. 5). As a result, for both spin injections, the zero-energy conductance have relatively large amplitude and the ZBCP in the total conductance can survive even with the pyp_{y}-wave subdominant component

In the d+isd+is-wave case, the in-gap conductance changes from the flat band to a s-shaped one as shown in Fig. 4(c), where the conductance does not depend on the injected spin. Even around ϕ=0\phi=0, the ABSs are lifted from eV=0eV=0 because the ss-wave pair potential does not have any node on the Fermi surface (see Fig. 5). Reflecting this nodeless structure, the slope of the in-gap conductance peak around ϕ=0\phi=0 is much larger than those for the d+ipd+ip-wave junction. As a result, the conductance at eV=0eV=0 of the d+isd+is-wave junction is greatly reduced by the subdominant component.

Refer to caption
Figure 6: Local density of states at the interface of (a) d+ipd+ip - and (b) d+isd+is-wave junctions. The results are normalized to its normal-state value. Differing from the differential conductance, the ZBCP in the LDOS is split by the subdominant pair potential regardless of the pairing symmetry of the subdominant pair potential. The parameters are set to the same values used in Figs. 2(a) and 2(b), respectively.

Contrary to the differential conductance, the LDOS reflects the splitting of the zero-energy peak owing to the subdominant pair potential. The LDOS at the interface of the d+ipd+ip - and d+isd+is-wave junctions are shown in Figs. 6(a) and 6(b). Comparing Figs. 6(a) and 2(a), we see that the zero-energy peak splits even in the d+ipd+ip -wave junction, where the ZBCP does not split. The zero-energy peak moves to E±TpE\sim\pm T_{p}. In GNSG_{\mathrm{NS}}, the surface state with the small angle (i.e., ky1k_{y}\ll 1) contributes more than those with large angles (i.e., |ky|kF|k_{y}|\sim k_{F}) because the conductance represents the electric current flowing in the xx-direction; the more perpendicular injection has the more contribution to the conductance (see the factor cosϕ\cos\phi in the angle integration in Eq. 44). On the other hand, the LDOS is not directly related to the transport. Thus, the channels with large angles also contribute to the LDOS. Although there are two high peaks in the LDOS of the d+ipd+ip -wave junction, a sharp but low peak appears at E=0E=0. The origin of this low peak is the same as in the conductance. The center of the LDOS peaks shift to the positive or negative side depending on the spin. However, the LDOS for both spin have a relatively large amplitude at E=0E=0 and make a zero-energy peak in the total LDOS.

The spontaneous edge currents in the d+ipd+ip- and d+isd+is-wave SCs are explained in Appendix B with focusing on the symmetry of the quasiclassical Green’s function. The spontaneous current is absent (present) in the d+ipd+ip-wave (d+isd+is-wave) SC.

III.2 Barrier-strength dependence

Refer to caption
Figure 7: Evolution of the zero-bias conductance peaks for (a) d+ipd+ip- and (b) d+isd+is-wave junctions. In (a) and (b), the barrier potential is set to. Z=1Z=1, 22, 33, 44, and 66. The calculated results are plotted with a shift of GNNG_{\mathrm{NN}} with increasing ZZ. The ZBCP for the d+ipd+ip-wave junction does not split regardless of the barrier strength, whereas the ZBCP for the d+isd+is-wave junction changes from a peak to finite-energy double peaks when Z2Z\geq 2. The spatial profiles of the pair potentials are shown in (c) and (d), where the subdominant components are plotted in the insets. In (c) and (d), the barrier potential is set to Z=1Z=1, 22, 33, and 66. The effective critical temperature for the subdominant components are set to Tp/Td=Ts/Td=0.25T_{p}/T_{d}=T_{s}/T_{d}=0.25.

The differential conductance in the presence of a subdominant component depends on the strength of the barrier potential Tanuma et al. (2001c). The evolution of the ZBCP is shown in Figs. 7(a) and 7(b), where the d+ipd+ip- and d+isthed+isthe-wave superconductor assumed in Figs. 7(a), and 7(b) respectively. The barrier potential ZZ changes asfollows: Z=1Z=1, 22, 33, 44, and 66. Effective critical temperature for the subdominant components are set to Tp/Td=Ts/Td=0.25T_{p}/T_{d}=T_{s}/T_{d}=0.25. The ZBCP for the d+ipd+ip-wave junction is present regardless of the strength of the barrier parameter ZZ. We have confirmed that the ZBCP does not split under even higher barrier potentials. In general, the position of the midgap conductance peak is not influenced by the barrier parameter ZZ. The larger barrier just results in the sharper spectra. Therefore, the low-angle contribution as discussed above can survive even with a large barrier potential.

The zero-bias conductance for the d+isd+is-wave is more sensitive to the barrier potential than that for that for the d+ipd+ip-wave junction. The amplitude of the zero-bias conductance reduces significantly with increasing ZZ. Even with a rather small barrier potential (e.g., Z=2Z=2), the two peaks appear at eV=0.25Δ0eV=0.25\Delta_{0}, which corresponds to the amplitude of the subdominant ss-wave pair potential. Namely, the split peak would be observed more frequently in high-TcT_{c} superconductor junctions if the ss-wave subdominant order is realized.

The barrier-potential dependence of the pair potentials for the d+ipd+ip- and d+isd+is-wave junctions are shown in Figs. 7(c) and 7(d), where the pp- and ss-wave subdominant components are shown in the insets. The barrier potential is set to Z=1Z=1, 22, 33, and 66. The dominant dd-wave pair potential is not strongly depend on ZZ. Their profiles for Z2Z\geq 2 are almost the same regardless the pairing symmetry of the subdominant components. The amplitudes of both of the subdominant pp- and ss-wave pair potentials increase with an increase in ZZ. The larger ZZ generates the more subdominant components reflecting the parity mixing by the inversion symmetry breaking.

III.3 Effects of short decay length

Refer to caption
Figure 8: Effect of short decay length of the subdominant component. The differential conductances and the profile of the pair potentials are shown in top and bottom panels respectively, where Tp/Td=1T_{p}/T_{d}=1 in (a) and (c), and Tp/Td=2T_{p}/T_{d}=2 in (b) and (d), respectively. We see that the ZBCP is present even when Tp>TdT_{p}>T_{d} and κ<ξ0\kappa<\xi_{0}.

The microscopic calculationsMatsubara and Kontani (2020a, b) indicates that the pp-wave attractive interaction may be very strong in the very vicinity of the interface. The decay length of surface pp-wave component may be much shorter than the superconducting coherence length and TpT_{p} may be larger than TdT_{d}. Such a short-range strong attractive interaction can be modeled by increasing TpT_{p}, and by introducing the decay parameter κ\kappa [see Eq. (22)]: The differential conductance and pair potentials with a short-range strong attractive potential is shown in Figs. 8(a) and 8(b). The results show that the ZBCP is not split by the subdominant pair potential even when the attractive potential is much larger than that for the dominant dd-wave. With increasing decay parameter, the ZBCP becomes broader because the influences from the subdominant potential becomes larger.

IV Discussion

We have confirmed that our conclusions on the ZECP do not depend on the details of the potential at the interface. We have replaced the δ\delta-function insulating barrier with the rectangular one. The results with the rectangular potential (not shown) are qualitatively the same as those with the δ\delta-function one [e.g., Fig. 7(a)]; the ZBCP of the d+ipd+ip-wave junction does not split. Therefore, our conclusions are valid even when the interface potential has a finite width (i.e., more realistic model than the δ\delta-function barrier model).

The conductance spectra of cuprate superconductors observed in experiments to date have a peak at the zero energy Kashiwaya et al. (1995a, 1998); Alff et al. (1997); Wei et al. (1998); Biswas et al. (2002); Chesca et al. (2008); Bouscher et al. (2020), even though several experiments have reported splitting of the ZBCP Covington et al. (1997); Fogelström et al. (1997); Krupke and Deutscher (1999). Our theoretical study, where the pp-wave surface attractive interaction is phenomenologically taken into account, demonstrates that the pp-wave subdominant pair potential does not split the zero-bias peak. In particular, our results show that the microscopic theory Matsubara and Kontani (2020a, b) can be consistent with experimental results obtained to date.

The conductance spectrum of a d+ipd+ip-wave junction depends on the spin of the injected particle because of the mixture of the pp-wave spin-triplet and dd-wave spin-singlet pairs. Replacing the normal-metal electrode with a ferromagnetic metal will provide useful information for detecting the surface subdominant pair potential. Investigating how the pp- and ss-wave subdominant pair potentials modify the conductance spectra would be interesting.

In this paper, we have studied the transport property of the d+ipd+ip-wave junction in the ballistic limit by calculating the tunneling conductance. The induced pp-wave pair, however, is more fragile against impurity scatterings than are ss-wave pairs Suzuki and Asano (2015); Yamada et al. (1996); Poenicke et al. (1999); Zare et al. (2008); Suzuki and Asano (2016). Thus, in the presence of disorder, the differential conductance of the d+ipd+ip- and d+isd+is-wave junctions may be different. Clarifying the effect of disorder would be important for applying our theory to experimental results.

V Conclusion

We have theoretically studied the conductance spectroscopy of normal-metal/dxyd_{xy}-wave superconductor junctions with the spin-triplet pyp_{y}-wave subdominant order at the interface utilizing the quasiclassical Eilenberger formalism. We have considered the ballistic junction, where a δ\delta-function-type insulating barrier exists at the interface. The conductance spectra are calculated using the self-consistent pair potentials.

The calculated conductance spectra show that the ZBCP originating from the dxyd_{xy}-wave pair potential is not split by the pyp_{y}-wave subdominant pair potential at the interface, in contrast to the ss-wave subdominant component, which is known to split the ZBCP. The pyp_{y}-wave pair potential has nodes at ky=0k_{y}=0, which does not affect the zero-energy states around ky=0k_{y}=0. The contributions from these channels form the ZBCP in the conductance spectra, even in the presence of the pyp_{y}-wave subdominant pair potential.

In addition, we have studied the effect of the pyp_{y}-wave subdominant pair potential on the dispersion of the surface states of the dxyd_{xy}-wave SC. The pyp_{y}-wave subdominant component changes the zero-energy flat band formed with the Andreev bound states to a V-shape or inverted V-shape, depending on the spin subspace. The spin-subspace dependence stems from the coexistence of the spin-singlet and spin-triplet pair potentials near the interface.

Acknowledgements.
The authors would like to thank S. Matsubara, S. Kashiwaya, H. Kontani, and Y. Maeno for the useful discussions. This work was supported by Grants-in-Aid from JSPS for Scientific Research on Innovative Areas “Topological Materials Science” (KAKENHI Grant Numbers JP15H05851, JP15H05852, JP15H05853 and JP15K21717), Scientific Research (A) (KAKENHI Grant No. JP20H00131), Scientific Research (B) (KAKENHI Grant Numbers JP18H01176 and JP20H01857), Japan-RFBR Bilateral Joint Research Projects/Seminars number 19-52-50026, and the JSPS Core-to-Core program “Oxide Superspin” international network.

Appendix A Profile of the pair potential

The profiles of the pair potentials of the d+ipd+ip- and d+isd+is-wave junctions are shown in Fig. 9(a) and 9(b), respectively. The pair potentials are normalised by that in a homogeneous dd-wave superconductor (i.e., Δ¯p=Δp(s)/Δd|x\bar{\Delta}_{p}={\Delta}_{p(s)}/\Delta_{d}|_{x\to\infty}). The parameters are set to the same values used in Fig. 2. The amplitude of the subdominant pair potential depends on the effective critical temperature TpT_{p} and TsT_{s}. The The pp-wave subdominant pair potential is slightly larger than the ss-wave one. The subdominant component affects slightly on the dd-wave dominant component. However, the effect is negligible.

Refer to caption
Figure 9: Spatial dependences of the pair potentials in (a) d+ipd+ip- and (b) d+isthed+isthe-wave junctions. The parameters are set to the same values used in Fig. 2.

Appendix B Spontaneous charge current

The Eilenberger equation (1) can be rewritten as

iαvFxxgˇ+[ˇ,gˇ]=0,\displaystyle i\alpha v_{F_{x}}\partial_{x}\check{g}+[\check{\mathcal{H}},\check{g}]_{-}=0, (47)
ˇ(x,α,ϕ,iωn)=[iωnσ^0Δ^αΔ^αiωnσ^0],\displaystyle\check{\mathcal{H}}(x,\alpha,\phi,i\omega_{n})=\left[\begin{array}[]{cc}i\omega_{n}\hat{\sigma}_{0}&\hat{\Delta}_{\alpha}\\ -\hat{\Delta}_{\alpha}^{\dagger}&-i\omega_{n}\hat{\sigma}_{0}\end{array}\right], (50)

where gˇ=gˇαα\check{g}=\check{g}_{\alpha\alpha}. In this section, we make α\alpha explicit only when necessary. The current density in the yy-direction can be obtained from the Green’s function:

jy(x)\displaystyle j_{y}(x) =evFN0πiβωnkyTr[g^(x,ky,iωn)],\displaystyle=ev_{F}N_{0}\frac{\pi}{i\beta}\sum_{\omega_{n}}\langle k_{y}\mathrm{Tr}\left[\hat{g}(x,k_{y},i\omega_{n})\right]\rangle, (51)

where e<0e<0 is the charge of a quasiparticle, ky=sinϕk_{y}=\sin\phi, and β=1/T\beta=1/T. Using the basic symmetry of the Green’s function gˇ(x,α,ϕ,iωn)=τˇ3{gˇ(x,α,ϕ,iωn)}τˇ3\check{g}(x,\alpha,\phi,i\omega_{n})=-\check{\tau}_{3}\left\{\check{g}(x,\alpha,\phi,-i\omega_{n})\right\}^{\dagger}\check{\tau}_{3}, we can reduce the current density into the form

jyj0\displaystyle\frac{j_{y}}{j_{0}} =TTdωn>0kyIm{Tr[g^]},\displaystyle=\frac{T}{T_{d}}\sum_{\omega_{n}>0}\langle k_{y}\mathrm{Im}\{\mathrm{Tr}\left[\hat{g}\right]\}\rangle, (52)
=TTdωn>0α0π/2Im{Tr[g^(x,α,ϕ,iωn)\displaystyle=\frac{T}{T_{d}}\sum_{\omega_{n}>0}\sum_{\alpha}\int_{0}^{\pi/2}\mathrm{Im}\{\mathrm{Tr}[\hat{g}(x,\alpha,\phi,i\omega_{n})
g^(x,α,ϕ,iωn)]}sinϕdϕ,\displaystyle\hskip 73.97716pt-\hat{g}(x,\alpha,-\phi,i\omega_{n})]\}\sin\phi\,d\phi, (53)

where j0=2πevFN0Tdj_{0}=2\pi ev_{F}N_{0}T_{d}. In Eq. (53), we have divided the interval of integration into two regions.

The matrices ˇ\check{\mathcal{H}} for the dxyd_{xy}-wave SC can be written as

ˇ\displaystyle\check{\mathcal{H}} =[iωnσ^0iσ^2Δdsin(2ϕ)iσ^2Δdsin(2ϕ)iωnσ^0],\displaystyle=\left[\begin{array}[]{cc}i\omega_{n}\hat{\sigma}_{0}&i\hat{\sigma}_{2}\Delta_{d}\sin(2\phi)\\ i\hat{\sigma}_{2}\Delta_{d}^{*}\sin(2\phi)&-i\omega_{n}\hat{\sigma}_{0}\end{array}\right], (56)

which satisfies the symmetry relation

ˇ(x,α,ϕ,iωn)=τˇ2[ˇ(x,α,ϕ,iωn)]τˇ2.\displaystyle\check{\mathcal{H}}(x,\alpha,\phi,i\omega_{n})=\check{\tau}_{2}\left[\check{\mathcal{H}}(x,\alpha,-\phi,i\omega_{n})\right]^{*}\check{\tau}_{2}. (57)

This relation means that the Green’s function has the symmetry in the particle-hole space gˇ(x,α,ϕ,iωn)=τˇ2[gˇ(x,α,ϕ,iωn)]τˇ2\check{g}(x,\alpha,\phi,i\omega_{n})=\check{\tau}_{2}\left[\check{g}(x,\alpha,-\phi,i\omega_{n})\right]^{*}\check{\tau}_{2}, meaning that

g^(x,α,ϕ,iωn)=[g^(x,α,ϕ,iωn)].\displaystyle\hat{g}(x,\alpha,\phi,i\omega_{n})=-\left[\hat{g}(x,\alpha,-\phi,i\omega_{n})\right]^{*}. (58)

Substituting Eq. (58) into (53), we can demonstrate that no spontaneous current flows at a surface of a dxyd_{xy}-wave SC without a subdominant pair potential.

The matrices ˇ\check{\mathcal{H}} for the d+ipd+ip- and d+isd+is-wave SCs can be written as

ˇp\displaystyle\check{\mathcal{H}}_{p} =[iωnσ^0iσ^2Δdsin(2ϕ)+σ^1iΔpsinϕiσ^2Δdsin(2ϕ)+σ^1iΔpsinϕiωnσ^0],\displaystyle=\left[\begin{array}[]{cc}i\omega_{n}\hat{\sigma}_{0}&i\hat{\sigma}_{2}\Delta_{d}\sin(2\phi)+\hat{\sigma}_{1}i\Delta_{p}\sin\phi\\ i\hat{\sigma}_{2}\Delta_{d}^{*}\sin(2\phi)+\hat{\sigma}_{1}i\Delta_{p}^{*}\sin\phi&-i\omega_{n}\hat{\sigma}_{0}\end{array}\right], (61)
ˇs\displaystyle\check{\mathcal{H}}_{s} =[iωnσ^0iσ^2{Δdsin(2ϕ)+iΔs}iσ^2{Δdsin(2ϕ)+iΔs}iωnσ^0].\displaystyle=\left[\begin{array}[]{cc}i\omega_{n}\hat{\sigma}_{0}&i\hat{\sigma}_{2}\left\{\Delta_{d}\sin(2\phi)+i\Delta_{s}\right\}\\ i\hat{\sigma}_{2}\left\{\Delta_{d}^{*}\sin(2\phi)+i\Delta_{s}^{*}\right\}&-i\omega_{n}\hat{\sigma}_{0}\end{array}\right]. (64)

We can show that the matrix ˇp\check{\mathcal{H}}_{p} satisfies Eq. (57), whereas ˇs\check{\mathcal{H}}_{s} does not due to Δs\Delta_{s}. Namely, we can demonstrate that no spontaneous charge current flows in the d+ipd+ip-wave case, whereas the current flows spontaneously in the d+isd+is-wave case.

References