Basic quantities of the Equation of State in isospin asymmetric nuclear matter
Abstract
Based on the Hugenholtz-Van Hove theorem, six basic quantities of the EoS in isospin asymmetric nuclear matter are expressed in terms of the nucleon kinetic energy , the isospin symmetric and asymmetric parts of the single-nucleon potentials and . The six basic quantities include the quadratic symmetry energy , the quartic symmetry energy , their corresponding density slopes and , and the incompressibility coefficients and . By using four types of well-known effective nucleon-nucleon interaction models, namely the BGBD, MDI, Skyrme, and Gogny forces, the density- and isospin-dependent properties of these basic quantities are systematically calculated and their values at the saturation density are explicitly given. The contributions to these quantities from , , and are also analyzed at the normal nuclear density . It is clearly shown that the first-order asymmetric term (also known as the symmetry potential in Lane potential) plays a vital role in determining the density dependence of the quadratic symmetry energy . It is also shown that the contributions from high-order asymmetric parts of the single-nucleon potentials ( with ) cannot be neglected in the calculations of the other five basic quantities. Moreover, by analyzing the properties of asymmetric nuclear matter at the exact saturation density , the corresponding quadratic incompressibility coefficient is found to have a simple empirical relation .
pacs:
21.30.Fe, 21.65.Cd, 21.65.Ef, 21.65.MnI Introduction
Research on the isospin- and density-dependent properties of the equation of state (EoS) in isospin asymmetric nuclear matter is a longstanding issue in both nuclear physics and astrophysics PDan02 ; JML04 ; MBal16 ; CJJ21 . With respect to the exchange symmetry between protons and neutrons, the EoS for asymmetric nuclear matter can be expressed as an even series of isospin asymmetry , in which the first term is the energy per nucleon in symmetric nuclear matter and the coefficients of the isospin-dependent terms are known as the -th order symmetry energy . In recent years, the EoS of nuclear matter has been extensively studied by (I) microscopic and phenomenological many-body approaches MB03 ; HY20 ; XLR21 ; JXU21 ; (II) the observables from heavy-ion reactions GC14 ; LWC14 ; JMDONG13 ; JXu09 ; GFWei20 ; OL09 ; (III) the astrophysical observations LiBA19 ; NBZhang-NST-18 ; YXU19 . For symmetric nuclear matter, the saturation density is constrained in a relatively narrow region fm-3 and the corresponding energy per nucleon is approximately MeV LiBA08 . The incompressibility coefficient has a generally accepted value of MeV constrained by theoretical approaches and the giant monopole resonance data DHY99 ; JPB80 ; SS06 . In addition, the skewness was recently found to have significant effects on the structures of neutron stars, but its value was scattered widely from MeV to MeV BJCai17 ; NBZ18 ; WJX19 . For asymmetric nuclear matter, the value of the quadratic symmetry energy is constrained to be MeV LiBA13 ; MOer17 . However, its density slope and the incompressibility coefficient remain uncertain, i.e. MeV LiBA13 ; MOer17 and UGar07 ; TLi07 ; MLQ88 . It should be emphasized that, at both sub-saturation and supra-saturation densities, the quadratic symmetry energy is not well constrained, especially at supra-saturation densities ZGXIAO09 ; LWC07 ; CXu12CPL ; NBZhang17 . The quartic symmetry energy is predicted to be less than MeV JP17 ; ZWL18 ; JMDONG18 . In contrast to the quadratic one, few studies have been conducted on the quartic density slope and the corresponding incompressibility coefficient CGB17 .
In the present work, we perform a systematic analysis of six basic quantities in the EoS based on the Hugenholtz-Van Hove (HVH) theorem NMH58 , namely the , , , , , and . Among them, the properties of , , and their slopes and were re-analyzed CXu11 ; NW17 ; CXu14 ; NW16 ; MJ21 . The analytical expressions of the incompressibility coefficients and in terms of single-nucleon potentials are given for the first time. In the literature, there are various effective interaction models: transport models such as the Bombaci-Gale-Bertsch-Das Gupta (BGBD) interaction CG87 ; IB91 ; CBD03 ; JR04 , the isospin- and momentum-dependent MDI interaction CBD03 ; LiBA04a ; LiBA04b ; LWC05c , and the Lanzhou quantum molecular dynamics (LQMD) model ZQFENG11 ; ZQFENG12 ; FZHang20 , the self-consistent mean-field approach including the zero-range momentum-dependent Skyrme interaction THRS59 ; DV72 ; YZWANG19 , the finite-range Gogny interaction DMB67 ; JD75 ; DG77 and the relativistic mean-field model BOGUTA77 ; FO13 , etc.. The values of these quantities at the saturation density are calculated using two types of BGBD interactions, the MDI interactions with , and , sets of the Skyrme interactions MD12 ; GSkI ; KDE0v1 ; LNS ; MSL0 ; AWS05 ; SKRA ; SkT1 ; Skxs20 ; SQMC650 ; SV-sym32 , and sets of the Gogny interactions JFB91 ; FC08 ; SG09 . By taking the NRAPR Skyrme interaction as an example, we show the isospin- and density-dependent properties of the EoS for asymmetric nuclear matter explicitly. Meanwhile, for symmetric nuclear matter, , , and are also analyzed in detail. It should be emphasized that the skewness was recently found to be closely related to not only the maximum mass of neutron stars but also the radius of canonical neutron stars, and the calculations on in the present work might be helpful in further determining the properties of neutron stars. In particular, the contributions from the high-order terms of the single-nucleon potential and to these basic quantities are evaluated in detail.
The paper is organized as follows. In Sec. II, based on the HVH theorem, we express the basic quantities of the EoS in terms of the nucleon kinetic energy and the symmetric and asymmetric parts of the single-nucleon potential. The isospin-dependent saturation properties of the asymmetric nuclear matter are also discussed. In Sec. III, the calculated results by using four different effective interaction models are given. Finally, a summary is presented in Sec. IV.
II Decomposition of basic quantities of EoS in terms of global optical potential components
II.1 Basic quantities in the Equation of State of asymmetric nuclear matter

For isospin asymmetric nuclear matter, the EoS can be expanded as a series of isospin asymmetry . If the high-order terms are neglected, it can be expressed as (see Fig. 1). Each term can be further expanded around the saturation density of symmetric nuclear matter as a series of a dimensionless variable , which characterizes the deviations of the nuclear density from . The density slope and incompressibility coefficient of the -th order symmetry energy are defined as and , respectively. The skewness of the EoS for symmetric nuclear matter is given by .
II.2 The Hugenholtz-Van Hove (HVH) theorem and decomposition of basic quantities of asymmetric nuclear matter
Relating the Fermi energy and the energy per nucleon , the general Hugenholtz-Van Hove (HVH) theorem can be written as NMH58
(1) |
where and are the energy density and pressure of the fermion system at an absolute temperature of zero. Accordingly, the Fermi energies of neutrons and protons in asymmetric nuclear matter can be expressed as CXu11
(2a) | |||
(2b) |
where and are the kinetic energy and the single-nucleon potential of the neutron/proton with the Fermi momentum . Furthermore, can be expanded by a series of the isospin asymmetry as
(3) |
where is for the neutron and for the proton, and and are the symmetric and asymmetric parts, respectively. In particular, and are called isoscalar and isovector (symmetry) potentials in the popular Lane potential AM62 .
By subtracting Eq. (2b) from Eq. (2a), one can obtain
(4) |
Expressing both sides of Eq. (4) in terms of and comparing the coefficients of and , we can obtain the general expressions of the quadratic and quartic symmetry energies as
(5a) | ||||
(5b) |
By adding Eqs. (2a) to (2b), expanding both sides of this summation in terms of , and comparing the coefficients of , we can obtain an important relationship between and its density slope
(6) |
where is defined as and can be rewritten as
(7) |
Obviously, and can be calculated from the energy density of symmetric nuclear matter . Simultaneously, the general expressions of the density slopes and can also be given by comparing the coefficients of and , namely,
(8a) | ||||
(8b) |
II.3 The exact saturation density as a function of isospin asymmetry
For isospin asymmetric nuclear matter, the saturation density is different from that of the symmetric nuclear matter . The former is defined as the exact saturation density and can be also written as a function of the isospin asymmetry LWC09
(11) |
For symmetric nuclear matter with , the is reduced to . According to the property of the saturation point and expanding the EoS in terms of , the exact saturation density can be expressed as
(12) |
At the exact saturation density , the energy per nucleon of asymmetric nuclear matter is given by
(13) |
The corresponding incompressibility coefficient of the EoS is
(14) |
It is clearly shown that the quartic symmetry energy at the exact saturation density is , and the quadratic incompressibility coefficient is
(15) |
In previous studies LiBA08 ; MLQ88 , the is approximated as by neglecting the term for simplicity. We will discuss its effect on in the following section.
III Results and discussions
We performed a systematic analysis of the basic quantities in the EoS of both symmetric and asymmetric nuclear matter at the saturation density by using interaction parameter sets, which include two BGBD interactions with different neutron-proton effective masses CG87 ; IB91 ; CBD03 ; JR04 , the MDI interaction with , , and CBD03 ; LiBA04a ; LiBA04b ; LWC05c , the Skyrme interactions MD12 ; GSkI ; KDE0v1 ; LNS ; MSL0 ; AWS05 ; SKRA ; SkT1 ; Skxs20 ; SQMC650 ; SV-sym32 , and four Gogny interactions JFB91 ; FC08 ; SG09 . It is known that most of these interactions are fitted to the properties of finite nuclei, and the extrapolations to abnormal densities can be rather diverse. However, the comparison of a large number of results from different interactions could possibly provide useful information on the tendency of the density dependence of these basic quantities. Detailed numerical results from total interaction parameter sets are summarized in Table 1. The average values of the basic quantities in the EoS are also given. For comparison, we also list the constraints summarized in other studies (see the last row of Table 1). As shown in Table 1, the calculated values of , , , and are consistent with the constraints extracted from both theoretical calculations and experimental data LiBA08 ; SS06 ; LiBA13 ; MOer17 . Interestingly, the averaged value is almost the same as the constraint in Ref. LWC09 . To further estimate the error bars of these basic quantities, all the calculated values in Table 1 are plotted in Figs. 2 and 3. It is seen from Fig. 2 that the data points of and are well constrained in a narrow range and the corresponding error bars are small. The error bar of skewness MeV is relatively large, especially for the Gogny interactions. It is also noted that the skewness, together with , has recently received much attention in the calculations of the neutron stars’ maximum mass and the radius of canonical neutron stars LiBA19 ; NBZ18 ; WJX19 . The error bars of the high-order terms , and are also given, i.e. MeV, MeV, and MeV. In addition, for the MDI interaction, the and values with different spin(isospin)-dependent parameter are scattered over a wide range. This is because the different choices of parameter are to simulate very different density dependences of the symmetry energies at high densities CBD03 ; LiBA04a ; LiBA04b .
Force | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|
BGBD | ||||||||||
Case-1 | 0.160 | -15.8 | 215.9 | -447.5 | 32.9 | 87.9 | -32.7 | 1.72 | 6.82 | 7.14 |
Case-2 | 0.160 | -15.8 | 215.9 | -447.5 | 33.0 | 121.8 | 101.0 | -0.73 | -4.26 | 7.14 |
MDI | ||||||||||
0.160 | -16.1 | 212.4 | -447.3 | 30.5 | 14.7 | -264.0 | 0.62 | 0.53 | -4.83 | |
0.160 | -16.1 | 212.4 | -447.3 | 30.5 | 60.2 | -81.7 | 0.62 | 0.53 | -4.83 | |
0.160 | -16.1 | 212.4 | -447.3 | 30.5 | 105.8 | 100.6 | 0.62 | 0.53 | -4.83 | |
Skyrme | ||||||||||
GSKI | 0.159 | -16.0 | 230.3 | -405.7 | 32.0 | 63.5 | -95.3 | 0.38 | 0.56 | -1.61 |
GSKII | 0.159 | -16.1 | 234.1 | -400.2 | 30.5 | 48.6 | -158.3 | 0.92 | 3.26 | 3.80 |
KDE0v1 | 0.165 | -16.2 | 228.4 | -386.3 | 34.6 | 54.7 | -127.4 | 0.46 | 0.92 | -0.94 |
LNS | 0.175 | -15.3 | 211.5 | -384.0 | 33.5 | 61.5 | -127.7 | 0.82 | 2.67 | 2.44 |
MSL0 | 0.160 | -16.0 | 230.0 | -380.3 | 30.0 | 60.0 | -99.3 | 0.81 | 2.70 | 2.66 |
NRAPR | 0.161 | -15.9 | 226.6 | -364.1 | 32.8 | 59.7 | -123.7 | 0.96 | 3.41 | 4.09 |
Ska25s20 | 0.161 | -16.1 | 221.5 | -415.0 | 34.2 | 65.1 | -118.2 | 0.46 | 0.93 | 0.88 |
Ska35s20 | 0.158 | -16.1 | 240.3 | -378.6 | 33.5 | 64.4 | -120.9 | 0.45 | 0.90 | -0.90 |
SKRA | 0.159 | -15.8 | 216.1 | -377.2 | 31.3 | 53.0 | -138.8 | 0.95 | 3.39 | 4.07 |
SkT1 | 0.161 | -16.0 | 236.1 | -383.5 | 32.0 | 56.2 | -134.8 | 0.46 | 0.91 | -0.91 |
SkT2 | 0.161 | -15.9 | 235.7 | -382.6 | 32.0 | 56.2 | -134.7 | 0.46 | 0.91 | -0.91 |
SkT3 | 0.161 | -15.9 | 235.7 | -382.7 | 31.5 | 55.3 | -132.1 | 0.46 | 0.91 | -0.91 |
Skxs20 | 0.162 | -15.8 | 202.4 | -426.5 | 35.5 | 67.1 | -122.5 | 0.53 | 1.27 | -0.22 |
SQMC650 | 0.172 | -15.6 | 218.2 | -376.9 | 33.7 | 52.9 | -173.2 | 1.05 | 3.82 | 4.77 |
SQMC700 | 0.171 | -15.5 | 220.7 | -369.9 | 33.5 | 59.1 | -140.8 | 0.97 | 3.44 | 4.03 |
SV-sym32 | 0.159 | -15.9 | 232.8 | -378.3 | 31.9 | 57.0 | -148.2 | 0.89 | 3.11 | 3.50 |
Gogny | ||||||||||
D1 | 0.166 | -16.4 | 227.2 | -446.9 | 30.7 | 18.6 | -273.6 | 0.76 | 1.75 | -1.78 |
D1S | 0.163 | -16.0 | 201.8 | -508.4 | 31.1 | 22.5 | -241.0 | 0.44 | -0.51 | -7.56 |
D1N | 0.161 | -16.0 | 224.5 | -430.9 | 29.6 | 33.6 | -168.2 | 0.21 | -1.95 | -11.80 |
D1M | 0.165 | -16.0 | 226.2 | -466.9 | 28.6 | 24.8 | -133.3 | 0.69 | -1.05 | -20.81 |
Average | 0.162 | -15.94 | 222.8 | -411.3 | 32.0 | 57.0 | -123.6 | 0.64 | 1.42 | -1.25 |
Constraint | -16 | 240 | 31.7 | 58.7 | 0.62 | |||||
Ref. | LiBA08 | SS06 | LiBA13 ; MOer17 | LiBA13 ; MOer17 | LWC09 |




In Fig. 4, we show the magnitudes of the separated terms , , as well as the total one at two different densities ( and ) and three different isospin asymmetries (=, and ) by taking the NRAPR Skyrme interaction as an example. At the saturation density (see graphs (a)-(c)), the contribution of to is dominant. The contribution of increases with an increase in isospin asymmetry . It is also shown that the contribution from is small and comes into play at large isospin asymmetry with . At (see graphs (d)-(f)), contribution is suppressed compared with that at , while plays a more important role in the EoS, especially at . It should also be noted that the contributes only at very high density and large isospin asymmetry. The magnitude of can significantly affect the calculation of the proton fraction in neutron stars at -equilibrium JXu09 ; CXu11 .
We further expand , , and as a series of with their corresponding slopes and the incompressibility coefficients. In Fig. 5, we depict the contributions from each term at different densities , and . As can be seen from Fig. 5, the first-order terms (), (), and () contribute largely at all densities. and terms become increasingly important with increasing density. For and at , the contributions from their slopes ( and ) and the incompressibility coefficients ( and ) are much larger than those at and . In particular, the , , and terms at can be as important as the first-order terms. Thus, high-order terms should be considered when analyzing the properties of nuclear matter systems at high densities, such as the neutron stars.


More interestingly, the basic quantities at the saturation density are decomposed into the kinetic energy and the symmetric and asymmetric parts of the single-nucleon potential and . As shown in Fig. 6, the contributions from different terms , and are denoted by superscripts of , , , , and , respectively. It is clear that the , , and are completely determined by and . For other quantities, the contributions from the asymmetric parts , , , and cannot be neglected. It is clearly shown that the first-order term contributes to all the six basic quantities. The second-order term does not contribute to , but to its corresponding slope and the incompressibility coefficient . In principle, the term should also contribute to the fourth-order terms , , and , but for the Skyrme interaction, is not momentum-dependent and does not contribute. In addition, there are very few studies on the contributions of high-order terms and to the basic quantities. In Fig. 7, we show the density-dependence of , , , , and at the Fermi momentum by using the NRAPR Skyrme interaction. It can be clearly seen from Fig. 7 that the magnitudes of and are generally very large, while the ones of , and are very small but increase with the increasing density. Our results indicate that the and contributions should be taken into account for the fourth-order terms to understand the properties of asymmetric nuclear matter, especially for the cases with very large isospin asymmetries and high densities.
Force | |||||||
---|---|---|---|---|---|---|---|
BGBD | |||||||
Case-1 | 0.160 | -0.195 | 0.038 | -16.17 | -560.1 | -377.9 | -2.07 |
Case-2 | 0.160 | -0.271 | 0.295 | -35.11 | -630.0 | -377.5 | -2.07 |
MDI | |||||||
0.160 | -0.033 | -0.040 | 0.11 | -352.2 | -321.2 | -2.11 | |
0.160 | -0.136 | -0.013 | -7.91 | -442.9 | -316.1 | -2.11 | |
0.160 | -0.239 | 0.237 | -25.73 | -534.2 | -311.4 | -2.11 | |
Skyrme | |||||||
GSKI | 0.159 | -0.131 | -0.024 | -8.36 | -476.03 | -364.23 | -1.76 |
GSKII | 0.159 | -0.099 | -0.056 | -4.12 | -450.04 | -366.94 | -1.71 |
KDE0v1 | 0.165 | -0.119 | -0.044 | -6.09 | -455.71 | -363.13 | -1.69 |
LNS | 0.175 | -0.153 | -0.059 | -8.12 | -496.75 | -385.10 | -1.82 |
MSL0 | 0.160 | -0.125 | -0.033 | -7.01 | -459.33 | -360.11 | -1.65 |
NRAPR | 0.161 | -0.127 | -0.050 | -6.90 | -481.82 | -385.91 | -1.61 |
Ska25s20 | 0.161 | -0.142 | -0.039 | -9.11 | -508.89 | -386.89 | -1.87 |
Ska35s20 | 0.158 | -0.127 | -0.039 | -8.19 | -507.47 | -405.95 | -1.58 |
SKRA | 0.159 | -0.117 | -0.058 | -5.55 | -456.89 | -364.36 | -1.75 |
SkT1 | 0.161 | -0.115 | -0.045 | -6.23 | -471.90 | -380.66 | -1.62 |
SkT2 | 0.161 | -0.115 | -0.045 | -6.23 | -471.62 | -380.45 | -1.62 |
SkT3 | 0.161 | -0.113 | -0.044 | -6.03 | -463.93 | -374.14 | -1.62 |
Skxs20 | 0.162 | -0.161 | -0.044 | -10.60 | -525.16 | -383.74 | -2.11 |
SQMC650 | 0.172 | -0.125 | -0.082 | -5.37 | -490.78 | -399.34 | -1.73 |
SQMC700 | 0.171 | -0.137 | -0.065 | -6.93 | -495.14 | -396.16 | -1.68 |
SV-sym32 | 0.159 | -0.117 | -0.057 | -6.10 | -490.44 | -397.74 | -1.62 |
Gogny | |||||||
D1 | 0.166 | -0.041 | -0.050 | 0.001 | -385.2 | -348.6 | -1.97 |
D1S | 0.163 | -0.055 | -0.056 | -0.81 | -376.0 | -319.3 | -2.52 |
D1N | 0.161 | -0.072 | -0.039 | -2.30 | -369.8 | -305.3 | -1.92 |
D1M | 0.165 | -0.054 | -0.023 | -0.67 | -282.1 | -230.9 | -2.06 |
Average | 0.162 | -0.125 | -0.017 | -7.98 | -465.4 | -360.1 | -1.86 |
Constraint | -500 | -370 / -550 | |||||
Ref. | LWC07 | LWC09 / UGar07 ; TLi07 |

By analyzing the isospin-dependence of the saturation properties of asymmetric nuclear matter, a number of important quantities are calculated using interaction parameter sets, and their numerical results as well as their averaged values are also listed in Table 2. For comparison, the constraints of and from other studies are listed in the last row of Table 2. It is shown that the second-order coefficient , one of the most important isospin-dependent parts of , has a negative value in all cases, and the fourth-order coefficient also has a negative value for the Skyrme and Gogny interactions. This means that in most cases, the saturation density of asymmetric nuclear matter is lower than that of symmetric nuclear matter, especially at larger isospin asymmetry (see graph (a) of Fig. 8). For the BGBD interaction (Case-2), the calculated value of is positive and relatively large. According to the relationship in Eq. (11), this would lead to a higher saturation density of asymmetric nuclear matter than that of symmetric nuclear matter with the isospin asymmetry close to unit. For asymmetric nuclear matter at , the corresponding values are rather diverse, which is considered to be important for the proton fraction in neutron stars.
As shown in graph (b) of Fig. 8, the results of , , and are given and their values are constrained to be MeV, MeV, and MeV, respectively. The averaged value is close to the previous theoretical constraint MeV given in Ref. LWC07 if the error bar is considered. In Table II, there are two previous constraints for . One is MeV from a modified Skyrme-like (MSL) model LWC09 , and the other is MeV by analyzing the measured data of the isotopic dependence of the giant monopole resonance (GMR) in the even-A Sn isotopes UGar07 ; TLi07 . Compared with these previous studies, it is clear that the and values remain uncertain and require more data to further constrain their values. In addition, as mentioned before, the term in Eq. (15) is typically ignored for simplicity. However, it is clearly shown in Fig. 8(b) that the contribution of this term is non-negligible. In the present work, we include the contribution of this high-order term, and the ratio is constrained in the range of . Finally we obtain a simple relation for
(16) |
With the averaged results MeV and MeV, the calculated value MeV is in good agreement with the average value of MeV from the interaction sets. This simple empirical relation could be useful for estimating the value of for asymmetric nuclear matter.
IV SUMMARY
Based on the Hugenholtz-Van Hove theorem, the general expressions for the six basic quantities of EoS are expanded in terms of the kinetic energy , the symmetric and asymmetric parts of global optical potential and . The analytical expressions of coefficients and are given for the fist time. By using kinds of interaction sets, the values of these quantities were systematically calculated at the saturation density . It is emphasized that there are very few studies on quantities , and and their average values from a total of interaction sets are MeV, MeV, and MeV, respectively. The averaged values of the other quantities weere consistent with those of previous studies. Furthermore, the different contributions of the kinetic term, the isoscalar and isovector potentials to these basic quantities were systematically analyzed at the saturation density. It is clearly shown that and play vital roles in determining the EoS of both symmetric and asymmetric nuclear matter. For asymmetric nuclear matter, the contributes to all the quantities, whereas does not contribute to , but contributes to the second-order terms and as well as the fourth-order terms , , and . The contribution from cannot be neglected for , , and . should also be included in the calculations for and . In addition, the quadratic incompressibility coefficient at is found to have a simple empirical relation based on the present analysis.
ACKNOWLEDGEMENTS
This work is supported by the National Natural Science Foundation of China (Grant No. 11822503).
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